Crystallography and Surface Oxidation of Stoichiometric Arsenopyrite from Šumadija-Kopaonik Pb-Zn/Polymetallic Ore District (Serbia)

Објеката

Тип
Рад у часопису
Верзија рада
објављена верзија
Језик
енглески
Креатор
Ivana Jelić, Aleksandar Pačevski, Aleksandar Kremenović, Aleš Šoster, Andreja Šestan, Janez Zavašnik
Извор
Crystals
Издавач
MDPI AG
Датум издавања
2023
Сажетак
The behaviour and stability of arsenopyrite largely depend on its crystal structure, but studies of crystallography and structural defects are scarce. For clarification, we investigated a series of natural arsenopyrite crystals from the polymetallic Pb-Zn-(±Cu,Ag,Au,Sb,Bi,W) Šumadija-Kopaonik ore district (Serbia) by powder X-ray diffraction (XRPD). Among them, samples from the Drenjak gold mineralisation showed near-stoichiometric FeAsS composition and were further investigated by conventional and high-resolution transmission electron microscopy methods. TEM revealed abundant planar crystallographic defects and epitaxial surface oxide layer formation upon air exposure. Our findings present the fundamental work on the prototype arsenopyrite structure and have further implications for studies on ion incorporation into FeAsS structure and its environmental stability and oxidation mechanisms as a source of anthropogenic As release into the environment.
том
13
Број
2
почетак странице
278
број страница
11
doi
10.3390/cryst13020278
issn
2073-4352
Subject
Inorganic Chemistry, Condensed Matter Physics,General Materials Science, General Chemical Engineering, crystal structure, FeAsS, oxidation, TEM, XRPD
Шира категорија рада
M20
Ужа категорија рада
М22
Права
Отворени приступ
Лиценца
Creative Commons – CC0 Public Domain
Формат
.pdf
Медија
crystals-13-00278.pdf

Ivana Jelić, Aleksandar Pačevski, Aleksandar Kremenović, Aleš Šoster, Andreja Šestan, Janez Zavašnik. "Crystallography and Surface Oxidation of Stoichiometric Arsenopyrite from Šumadija-Kopaonik Pb-Zn/Polymetallic Ore District (Serbia)" in Crystals, MDPI AG (2023). https://doi.org/10.3390/cryst13020278

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