Претрага
84 items
-
Some examples of interactions between certain rare earth elements and soil
... ability of soil to bind to itself a certain quantity of metallic ion until there comes to its saturation. Sorption capacity is represented by equation (1): q = (co - c1 /m)V (1) where q is sorption capacity (mg g-1), co initial metallic ions solution concentration (mg L-1), c1 equilibrium concentration ...
... and 1/n the line inclination.26 Table II presents the values of the initial mass of the metallic ion (x0) - the mass of ions in solutions divided by the mass of the sorbent and adsorbed mass of the metallic ion in the soil sample following agitation (x1). Acce pted M anuscr ipt 6 NIKOLOVSKI ...
... waste that contains these elements and to assume their fate in the environment. Keywords: Freundlich adsorption isotherm; sequential extraction, metallic ions, ICP-OES INTRODUCTION The demand in rare earth elements (REE) has been increasingly greater year in year out, as their application in military ...Zlatko Nikolovski, Jelena Isailović, Dejan Jeremić, Sabina Kovač, Ilija Brčeski. "Some examples of interactions between certain rare earth elements and soil" in Journal of the Serbian Chemical Society, National Library of Serbia (2021). https://doi.org/10.2298/JSC211006095N
-
The influence of Al<sup>3+</sup>ion on porcine pepsin activity<i>in vitro</i>
The in vitro effect of Al3þ ions in the concentration range 1.7·1026M–8.7·1023M on pepsin activity at pH 2, via kinetic parameters and its electrophoretic mobility was evaluated. Kinetic study demonstrated the existence of an activation effect of Al3þ at pH 2 on pepsin molecule. Kinetic analysis with respect to concentrations of haemoglobin showed that Al3þ ions increase the maximal velocity (Vmax) and kcat values rather than apparent affinity for substrate (KS) implying the non-competitive nature of activation which indicated ...... effects of chosen concentrations of AlP~ ions on 7 vitro pepsin activity are presented in Figure 1. It is obviously from Figure 1 that all investigated concentration of Al ions cause increase of pepsin activity. The increasing concentrations of metal ions induced increase of enzymatic activity ...
... activity of pepsin in the presence of AP * ions. Proteolytic activity of pepsin expressed as percentage depends on A ions present. The degree of activation is expressed as % of increased activity considering the activity of pepsin in the absence of Al ions as 100%. All results are expressed as a ...
... at increasing concentrations of Al ions resulted in a family of linear plots intersecting at 1/[Hb] axis (Figure 2). The Lineweaver-Burk plots show that increase of reaction velocity in the presence of ALP?* ions is proportional to increased AI? ions concentration. I/ V( HM / mi n} )' ...Vesna M. Pavelkić, Kristina R. Gopcević, Danijela Z. Krstić, Marija A. Ilić. "The influence of Al3+ion on porcine pepsin activityin vitro" in Journal of Enzyme Inhibition and Medicinal Chemistry, Informa UK Limited (2008). https://doi.org/10.1080/14756360701841095
-
Foreign molecules and ions in beryl obtained by infrared and visible spectroscopy
Jelić I., Logar M., Milošević M.. "Foreign molecules and ions in beryl obtained by infrared and visible spectroscopy" in Geophysical Research Abstracts Geophysical Research Abstracts 19, Vienna, Austria:Copernicus Publications (2017): 2479
-
Studying of Liquid Thermolysis Products of Various Types of Immature Kerogen in Sedimentary Lacustrine Rocks from the Valjevo-Mionica Basin, Serbia, and the Effect of Pt4+ and Ru3+ Ions on Their Yield and the Hydrocarbon Composition
Šajnović Aleksandra, Stojanović Ksenija, Simić Vladimir, Pevneva Galina S., Golovko Anatoly K., Jovančićević Branimir (2011)Šajnović Aleksandra, Stojanović Ksenija, Simić Vladimir, Pevneva Galina S., Golovko Anatoly K., Jovančićević Branimir. "Studying of Liquid Thermolysis Products of Various Types of Immature Kerogen in Sedimentary Lacustrine Rocks from the Valjevo-Mionica Basin, Serbia, and the Effect of Pt4+ and Ru3+ Ions on Their Yield and the Hydrocarbon Composition" in Geochemistry International 10 no. 49, Moscow, Russian Federation:Springer, M A I K Nauka - Interperiodica (2011): 1022-1034. https://doi.org/10.1134/S0016702911100053
-
Hydrochemical changes and groundwater grouping data by multivariate statistical methods within one karst system: recharge–discharge zone (Eastern Serbia case study)
Ljiljana Vasić, Dragana Živojinović, Vladana Rajaković-Ognjanović. "Hydrochemical changes and groundwater grouping data by multivariate statistical methods within one karst system: recharge–discharge zone (Eastern Serbia case study)" in Carbonates and Evaporites, Springer Science and Business Media LLC (2020). https://doi.org/10.1007/s13146-019-00548-6
-
Interactions of Copper(II) Complexes of some Schiff base ligands with calf thymus DNA and bovine serum albumin
Joni prelaznih metala u kombinaciji sa različitim ligandima nude veliki broj mogućnosti za ispitivanje potencijalnih bioaktivnosti. Među jonima prelaznih metala, bakar je poznat kao endogeni metal za ljude, sa karakterističnim biološkim redoks aktivnostima i relativno jakim afinitetom za nukleobaze. Kompleksi bakra ispoljavaju svoju antitumornu aktivnost na nekoliko različitih načina, generišu veliku količinu ROS, što uzrokuje oksidativno oštećenje mitohondrija i biomakromolekula. Nađeno je da kompleksi bakra(II) imaju umeren do dobar afinitet vezivanja sa DNK, uglavnom putem interkalacije.Angelina Petrović, Aleksandar Mijatović, Rada Baošić, Jovana Bogojeski. "Interactions of Copper(II) Complexes of some Schiff base ligands with calf thymus DNA and bovine serum albumin" in 6. Konferencija mladih hemičara Srbije, Srpsko hemijsko društvo (2018)
-
Microstructural and magnetic properties of electrospun hematite/cuprospinel composites
Phase composition, microstructural and magnetic properties of electrospun hematite/cuprospinel composites were investigated. Samples were synthesized starting with 0 to 10 mol% of copper relative to iron. The round shape of reference electrospun fbres was preserved upon their heating up to 600 °C in air, whereas at 700 °C hollow substructure was additionally formed. In these reference samples the presence of hematite phase was detected by XRPD. A small amount (traces) of Fe3O4 /γ-Fe2O3 was also found, due to the ...Electrical and Electronic Engineering, Condensed Matter Physics, Atomic and Molecular Physics and Optics, Electronic, Optical and Magnetic MaterialsMira Ristić, Aleksandar Kremenović, Michael Reissner, Željka Petrović, Svetozar Musić. "Microstructural and magnetic properties of electrospun hematite/cuprospinel composites" in Journal of Materials Science: Materials in Electronics, Springer Science and Business Media LLC (2020). https://doi.org/10.1007/s10854-020-03526-0
-
Hydrothermal Synthesized and Alkaline Activated Carbons Prepared from Glucose and Fructose—Detailed Characterization and Testing in Heavy Metals and Methylene Blue Removal
Sanja Krstić, Milan Kragović, Maja Pagnacco, Vladimir Dodevski, Branka Kaluđerović, Miloš Momčilović, Ivica Ristović, Marija Stojmenović (2018)glukoza, fruktoza, аktivni ugalj, hidrotermalni tretman, aktivacija hidroksida, teški metali, metilen plavo... indication that potassium ions may be inserted in the structure of the activated carbons and from that point potential available for ion exchange with heavy metal ions from surrounding aqueous solution. To confirm that, the testing of removal of different (model) heavy metal ions (Pb2+, Cd2+ and Zn2+) from ...
... adsorbed ~68 meq/100 g lead ions, ~13 meq/100 g Cd2+ and ~10 meq/100 g Zn2+ what is very comparable with results obtained from samples activated with KOH for lead ions, while glucose and fructose KOH activated samples removed significantly higher amounts of cadmium and zinc ions. Also, in these investigations ...
... and specific surface area (SBET ~700–1360 m2/g), a low degree of the crystal phase, indications that potassium ions may be included in heavy metals removal, good removal of the heavy metal ions (~47–59 mg/g for Pb2+, ~21–27 mg/g for Cd2+ and ~6–10 mg/g for Zn2+) and fast (~10–30 min) and good methylene ...Sanja Krstić, Milan Kragović, Maja Pagnacco, Vladimir Dodevski, Branka Kaluđerović, Miloš Momčilović, Ivica Ristović, Marija Stojmenović . "Hydrothermal Synthesized and Alkaline Activated Carbons Prepared from Glucose and Fructose—Detailed Characterization and Testing in Heavy Metals and Methylene Blue Removal" in Minerals, MDPI (2018)
-
The subthermal potential of karstic groundwater of Kučaj–Beljanica region in Serbia estimated by the multivariate analysis
Earth-Surface Processes, Geology, Pollution, Soil Science, Water Science and Technology, Environmental Chemistry, Global and Planetary ChangeLjiljana Vasić, Dragana Ž. Živojinovic, Vladana Rajaković-Ognjanović, Huang Fen, Cao Jianhua. "The subthermal potential of karstic groundwater of Kučaj–Beljanica region in Serbia estimated by the multivariate analysis" in Environmental Earth Sciences, Springer Science and Business Media LLC (2021). https://doi.org/10.1007/s12665-021-09392-1
-
Synthesis of MnCo2O4 nanoparticles as modifiers for simultaneous determination of Pb(II) and Cd(II)
The porous spinel oxide nanoparticles, MnCo2O4, were synthesized by citrate gel combustion technique. Morphology, crystallinity and Co/Mn content of modified electrode was characterized and determined by Fourier transform infra-red spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray diffraction pattern analysis (XRD), simultaneous thermogravimetry and differential thermal analysis (TG/DTA). Nanoparticles were used for modification of glassy carbon electrode (GCE) and new sensor was applied for simultaneous determination of Pb(II) and Cd(II) ions in water samples with the ...Vesna Antunović, Marija Ilić, Rada Baošić, Dijana Jelić, Aleksandar Lolić. "Synthesis of MnCo2O4 nanoparticles as modifiers for simultaneous determination of Pb(II) and Cd(II)" in PLOS ONE (2019). https://doi.org/10.1371/journal.pone.0210904
-
Comprehensive Profiling of Microbiologically Induced CaCO3 Precipitation by Ureolytic Bacillus Isolates from Alkaline Soils
Olja Šovljanski, Lato Pezo, Jovana Stanojev, Branimir Bajac, Sabina Kovač, Elvira Tóth, Ivan Ristić, Ana Tomić, Aleksandra Ranitović, Dragoljub Cvetković, Siniša Markov (2021)MICP process, kinetic study, calcite, vaterite, MALDI-TOF identification, Bacillus licheniformis, Sporosarcina pasteurii... slower, reducing the total concentration of calcium ions after a 3- and 5-day incubation period, respectively. In the case of B. muralis and B. simplex, instantaneous mineralization of calcium ions was not observed, and the concentration of free ions was lightly decreasing during incubation. It can be ...
... ureolysis kinetic pathway. 3.5. Evaluation of the MICP Efficiency In the presence of Urea and calcium ions in a nutrient medium, ureolytic bacteria have the opportunity to produce extracellular carbonate ions and induce precipitation of CaCO3 crystals. Moreover, morphology and an amount of precipitate are ...
... concluded that reduction kinetic for free calcium ions in accordance with the kinetic pathway of precipitation of calcium carbonate and pH changes during the MICP. Considering the fact that the negative charged bacterial walls act as absorbers for positive ions and mediate crystal formation as the center of ...Olja Šovljanski, Lato Pezo, Jovana Stanojev, Branimir Bajac, Sabina Kovač, Elvira Tóth, Ivan Ristić, Ana Tomić, Aleksandra Ranitović, Dragoljub Cvetković, Siniša Markov. "Comprehensive Profiling of Microbiologically Induced CaCO3 Precipitation by Ureolytic Bacillus Isolates from Alkaline Soils" in Microorganisms, MDPI AG (2021). https://doi.org/10.3390/microorganisms9081691
-
Sinteza i karakterizacija nanoprahova u CeO2-Bi2O3 sistemu
Marija D. Prekajski (2014-04-04)Nanoprahovi kristalnih faza iz serije čvrstih rastvora u pseudo-binarnom sistemuCeO2-Bi2O3 sintetisani su primenom jednostavne i ekonomične samopropagirajućemetode na sobnoj temperaturi korišćenjem nitrata metala i natrijum-hidroksida kaopolaznih supstanci. Osim krajnjih članova niza, CeO2 i niskotemperaturne polimorfnemodifikacije α-Bi2O3, sintetisani su i čvrsti rastvori nominalnog sastava Ce1-xBixO2-δ,gde je x = 0,1; 0,2; 0,3; 0,4; 0,5; 0,6; 0,7; 0,8; 0,9. Rezultati proučavanja metodomrendgenske difraktometrije na polikristalnom materijalu i ramanske spektroskopskeanalize pokazali su da su sintetisani prahovi sa nižim sadržajem bizmuta (x = 0,1 ...nanostrukturni materijali, čvrsti rastvori, CeO2, Bi2O3, rendgenskadifraktometrija praha, Ritveldova metoda, mikrostrukrurna analizaMarija D. Prekajski. "Sinteza i karakterizacija nanoprahova u CeO2-Bi2O3 sistemu" in Универзитет у Београду, Универзитет у Београду, Рударско-геолошки факултет (2014-04-04)
-
Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles
Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović (2013)Kinetika i mehanizam reakcija supstitucije između [Ru(trpi)(bpi)Cl]+ sa nukleofilima gvanozin-5′-monofosfatom, L-histidinom, tioureom i dimetilsulfoksidom proučavani su spektrofotometrijski u 0,1 M NaClO4 na 310 K. Red reaktivnosti za odabrane ligande je: tiourea > gvanozin-5′-monofosfat > L-histidin > DMSO. Ovaj red je povezan sa elektronskim, strukturnim i hemijskim karakteristikama kompleksa i nukleofila. Reakcija supstitucije sa tioureom je proučavana na tri različite temperature (288, 298 i 310 K). Negativna entropija aktivacije DS = potvrđuje asocijativni način aktivacije. Formiranje kompleksa [Ru(trpi)(bpi)H2O]2+ sa ligandima ...... coordinated to metal ions via amino, imidazole, and car- boxylate groups. In biological systems, there are numerous metalloproteins in which metal ions are bound to an L-histidine through N1 or N3 atoms of imidazole. However, this amino acid can coordinate some metal ions via car- boxylate oxygen ...
... activity of cisplatin and its analogs and their several side effects have stimulated the search for other metal-based anticancer drugs with metal ions differ- ent from platinum [4, 5]. Ruthenium complexes are today the most promising compounds for the investigation of antitumor activity of meta ...
... ligands L-His and 50-GMP are biologically relevant molecules. Tu is commonly used as a ‘‘protective agent’’ for the better excretion of ‘‘soft’’ metal ions [3–5], while DMSO is already present in the structures of some Ru complexes, such as NAMI-A. Also, we studied the hydrolysis of [Ru(trpy)(bpy)H2O] ...Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović. "Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles" in Monatshefte für Chemie - Chemical Monthly, Springer Science and Business Media LLC (2013). https://doi.org/10.1007/s00706-013-1044-1
-
Hydrogeochemical distribution of Ca and Mg in groundwater in Serbia
Petar Papić, Jovana Milosavljević, Marina Ćuk, Rastko Petrović . "Hydrogeochemical distribution of Ca and Mg in groundwater in Serbia" in Groundwater: Occurrence and Significance for Human Health, CRC Press, Balkema - Taylor & Francis Group (2014)
-
Adsorption and degradation of some psychiatric drugs by sol-gel synthesized titania-based photocatalysts: influence of tungsten and sodium content
Nina L. Finčur, Maja J. Šćepanović, Mirjana Grujić-Brojčin, Biljana F. Abramović, Jugoslav B. Krstić, Aleksandar Kremenović, Tatjana Srećković, Aleksandar Golubović (2019)Mesoporous anatase nanopowders were doped with 0.05−0.5 mol% of W6, in order to obtain more efficient photocatalyst than TiO2 Degussa P25 in the degradation of amitriptyline (AMI) under simulated solar irradiation (SSI). Dominant XRPD peaks were ascribed to anatase phase, with additional peaks which could correspond to brookite, TiO2 bronze and sodium titanate, Na2Ti9O19. The Raman scattering measurements have confirmed anatase as dominant phase, with broad Raman feature at ~270 cm−1 possibly related to Ti–O–Na stretching vibration. All W-doped ...Sol-gel synthesis, Doped titania nanopowders, XRPD, Raman spectroscopy, Adsorption and photocatalytic degradation, Psychiatric drugsNina L. Finčur, Maja J. Šćepanović, Mirjana Grujić-Brojčin, Biljana F. Abramović, Jugoslav B. Krstić, Aleksandar Kremenović, Tatjana Srećković, Aleksandar Golubović. "Adsorption and degradation of some psychiatric drugs by sol-gel synthesized titania-based photocatalysts: influence of tungsten and sodium content" in Journal of Sol-Gel Science and Technology, Springer Science and Business Media LLC (2019). https://doi.org/10.1007/s10971-019-04925-4
-
Mechanosynthesis and structural characterization of nanocrystalline Ce1–Y O2– (x=0.1–0.35) solid solutions
Martin Fabián, Bratislav Antić, Vladimír Girman, Milica Vučinić-Vasić, Aleksandar Kremenović, Shigeru Suzuki, Horst Hahn, Vladimír Šepelák (2015)A series of nanostructuredfluorite-type Ce1–xYxO2–δ (0rxr0.35) solid solutions, prepared via highenergy milling of the CeO2/Y2O3mixtures, are investigated by XRD, HR-TEM, EDS and Raman spectroscopy. For thefirst time, complementary information on both the long-range and short-range structural features of mechanosynthesized Ce1–xYxO2–δ, obtained by Rietveld analysis of XRD data and Raman spectroscopy, is provided. The lattice parameters of the as-prepared solid solutions decrease with increasing yttrium content. Rietveld refinements of the XRD data reveal increase in microstrains in the host ceria ...Martin Fabián, Bratislav Antić, Vladimír Girman, Milica Vučinić-Vasić, Aleksandar Kremenović, Shigeru Suzuki, Horst Hahn, Vladimír Šepelák. "Mechanosynthesis and structural characterization of nanocrystalline Ce1–Y O2– (x=0.1–0.35) solid solutions" in Journal of Solid State Chemistry, Elsevier BV (2015). https://doi.org/10.1016/j.jssc.2015.06.027
-
Interaction of sodium dodecylsulfate (SDS) with homoionic montmorillonites: adsorption isotherms and metal-ion release
The interaction of dodecylsulfate anions (DS−) with homoionic Ca-, Mg-, Ni-, Cu-, Cd-, Pb- and Fe-montmorillonites were investigated. Mg- and Cd-montmorillonite do not adsorb DS−, and an anion exchange at the edges of the clay mineral does not take place. Three different adsorption processes are identified on the other montmorillonites: i) Fe-montmorillonite is covered with amorphous iron hydroxide, and DS−-anions are bound at positively charged sites. ii) On Ca- and Pb-montmorillonite DS− is precipitated as Me(DS)2. iii) On Ni- ...M. Ilic, J. Gonzalez, A. Pohlmeier, H. D. Narres, M. J. Schwuger. "Interaction of sodium dodecylsulfate (SDS) with homoionic montmorillonites: adsorption isotherms and metal-ion release" in Colloid Polymer Science, Springer Science and Business Media LLC (1996). https://doi.org/10.1007/BF00656626
-
Influence of Ag doping on the morphological and magnetic properties in CuO nanopowders
Maria Čebela, Uroš Čakar, Vesna Lojpur, Maja Milošević, Sanja Krstić, Vladimir Dodevski, Milena Rosić (2023)... sample. The Rietveld method for fitting refinement procedure was performed which showed the incorporation of Ag** ions in the CuO crystal lattice, where they substitute Cuž* ions. SQUID magnetometer was used for investigation of magnetic behavior of synthesized materials in temperature interval ...Maria Čebela, Uroš Čakar, Vesna Lojpur, Maja Milošević, Sanja Krstić, Vladimir Dodevski, Milena Rosić. "Influence of Ag doping on the morphological and magnetic properties in CuO nanopowders" in Programme ; and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia , Beograd : Institut za multidisciplinarna istraživanja, (2023)
-
A new copper(II) arsenate, Na2Cu3(AsO3OH)4·4H2O containing discrete [Cu3O12]18− units: Synthesis, crystal structure and magnetic properties
Single crystals of the new disodium tricopper(II) tetrakis(hydrogenarsenate(V)) tetrahydrate, Na2Cu3(AsO3OH)4·4H2O were grown under hydrothermal conditions. The compound was characterized by room-temperature single-crystal X-ray diffraction, SEM-EDS analysis, Raman spectroscopy and magnetic susceptibility measurements. Na2Cu3(AsO3OH)4·4H2O represents a new layered structure-type [space group P21/c, a = 8.7089(17), b = 9.7452(19), c = 9.3353(19) Å, β = 92.63(3)°, V = 791.4(3) Å3, Z = 4]. The layers are normal to [100] and are composed of the isolated Cu3O12 units interconnected by AsO3OH coordination ...Na2Cu3(AsO3OH)4•4H2O, хидротермална синтеза, кристална структура, хидрирани хидрокси-арсенати, магнетна својстваTamara Đorđević, Ljiljana Karanović, Zvonko Jagličić. "A new copper(II) arsenate, Na2Cu3(AsO3OH)4·4H2O containing discrete [Cu3O12]18− units: Synthesis, crystal structure and magnetic properties" in Journal of Solid State Chemistry, Elsevier BV (2018). https://doi.org/10.1016/j.jssc.2018.05.024
-
Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes
Reakcije supstitucije monofunkcionalnih kompleksa [(TLtBu)PdCl]+ i [Pd(tpdm)Cl]+, gde je TLtBu = 2,6-bis[(1,3-di-terc-butilimidazolin-2-imino)metil]piridin i tpdm = terpiridindimetan, sa nukleofilima kao što su: tiourea, I−, Br−, NO2−, piridin i dimetil-sulfoksid (DMSO) proučavani su u 0,1 M vodenom rastvoru NaClO4 u prisustvu 10 mM NaCl. Reakcije su sprovedene na tri različite temperature (288, 298 i 308 K) korišćenjem tehnike zaustavljenog protoka na različitim temperaturama. Reakcije supstitucije su praćene pod uslovima pseudo prvog reda sa velikim viškom nukleofila. Dobijeni rezultati pokazuju da kompleks ...... conditions. All substitution reactions were studied in 0.1 M NaClO4 aqueous solution. The NaClO4 was taken because it is well known that perchlorate ions do not coordinate to Pt(II) or Pd(II) in aqueous solution [27]. To the solution was added 10 mM NaCl to prevent the spontaneous hydrolysis of the complexes ...
... 24] so it shows the strongest nucleophilicity. Our results confirm this explanation. Better reactiv- ity of I� ion compared to that of Br� and NO2 � ions can be explained by different polarizability of these nucleophiles. Namely, iodide ion is the most polarized halide ion (4.7 � 10�24 cm3) [31], so it ...
... conditions. All substitution reactions were studied in 0.1 M NaClO, aqueous solution. The NaClO, was taken because it is well known that perchlorate ions do not coordinate to Pt(II) or Pd(II) in aqueous solution [27]. To the solution was added 10 mM NaCl to prevent the spontaneous hydrolysis of the complexes ...Aleksandar Mijatović, Jovana Bogojeski, Biljana Petrović, Živadin D. Bugarčić. "Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes" in Inorganica Chimica Acta, Elsevier BV (2011). https://doi.org/10.1016/j.ica.2011.11.031