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445 items
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Structural dissymmetrization of optically anisotropic Grs64±1Adr36±1Sps2 grandite from Meka Presedla (Kopaonik Mt., Serbia)
In this paper, grandite core with Grs64±1Adr36±1Sps2composition was crystallographically studied. This core represents zone A of the macroscopically visiblefive A–E zones of the optically anisotropic Grs58–64 Adr36–42Sps2 grandite. The applied procedure includes the detailed analysis of the powder diffraction patterns, and the Rietveld refinements of the crystal structures in a series of 18 space groups and two mixtures, which were followed by the comparative analysis of the R-values, site occupancy factors, and the bond lengths and angles. Synthesis of all ...Pavle Tančić, Aleksandar Kremenović, Predrag Vulić. "Structural dissymmetrization of optically anisotropic Grs64±1Adr36±1Sps2 grandite from Meka Presedla (Kopaonik Mt., Serbia)" in Powder Diffraction, Cambridge University Press (CUP) (2019). https://doi.org/10.1017/S0885715619000897
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Sinteza i strukturna karakterizacija novih cezijumskih i kalijumskih silikata sa elementima retkih zemalja
Predrag Z. Dabić (2022)Predmet i ciljevi naučnog istraživanja ove doktorske disertacije su sinteza i strukturna karakterizacija novih cezijumskih i kalijumskih silikata sa elementima retkih zemalja. Istraživanja su izvedena u okviru sistema SiO2–REE2O3–XF, gde REE predstavlja trovalentni katjon elementa retkih zemalja (Sc, Y, Sm, Eu, Gd, Ho, Er, Tm, Yb, Lu), dok X predstavlja jednovalentni katjon alkalnih metala (K, Cs). Rad na disertaciji bio je fokusiran na sintezu monokristala, određivanje kristalnih struktura, kao i na kristalografsko i kristalohemijsko ispitivanje sintetisanih monokristala. Monokristali su sintetisani ...alkalni silikati elemenata retkih zemalja, kristalna struktura, sinteza metodom fluksa, rendgenska difrakcija na monokristalu, elementi retkih zemaljaPredrag Z. Dabić. Sinteza i strukturna karakterizacija novih cezijumskih i kalijumskih silikata sa elementima retkih zemalja, Beograd : P. Dabić, 2022
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Three new Sr-bearing arsenates, hydrothermally synthesized in the system SrO–MO–As2O5–H2O (M2+ = Mg, Cu, Zn)
Tamara Đorđević, Ljiljana Karanović (2018)During systematic research on the mineral-related synthetic arsenates, with particular focus on their structural and spectroscopic classification, three new Sr-containing arsenates Sr2Mg(AsO4)2· 2H2O (1), Sr2Zn4(AsO4)4·H2O (2) and Sr2Cu7(AsO4)6 (3) have been synthesized under low-temperature hydrothermal conditions in the system SrO MO As2O5 H2O (M 2þ = Mg, Zn, Cu). Their crystal structures were determined using room-temperature single-crystal X-ray diffraction data and refined to the following R-values: 1– R1 = 0.025; 2– R1 = 0.030; 3– R1 = 0.035. Compounds ...стронцијум, арсен, арсенати, кристална структура, дифракција рендгенских зрака на монокристалима, хидротермална синтеза, Раманска спектроскопијаTamara Đorđević, Ljiljana Karanović. "Three new Sr-bearing arsenates, hydrothermally synthesized in the system SrO–MO–As2O5–H2O (M2+ = Mg, Cu, Zn)" in European Journal of Mineralogy, Schweizerbart (2018). https://doi.org/10.1127/ejm/2018/0030-2749
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Crystallography and Surface Oxidation of Stoichiometric Arsenopyrite from Šumadija-Kopaonik Pb-Zn/Polymetallic Ore District (Serbia)
Ivana Jelić, Aleksandar Pačevski, Aleksandar Kremenović, Aleš Šoster, Andreja Šestan, Janez Zavašnik (2023)The behaviour and stability of arsenopyrite largely depend on its crystal structure, but studies of crystallography and structural defects are scarce. For clarification, we investigated a series of natural arsenopyrite crystals from the polymetallic Pb-Zn-(±Cu,Ag,Au,Sb,Bi,W) Šumadija-Kopaonik ore district (Serbia) by powder X-ray diffraction (XRPD). Among them, samples from the Drenjak gold mineralisation showed near-stoichiometric FeAsS composition and were further investigated by conventional and high-resolution transmission electron microscopy methods. TEM revealed abundant planar crystallographic defects and epitaxial surface oxide layer ...Inorganic Chemistry, Condensed Matter Physics,General Materials Science, General Chemical Engineering, crystal structure, FeAsS, oxidation, TEM, XRPD... into the crystal structure and direct microscopic obser- vation of the structural features of the same region. The crystal structure of investigated arsenopyrite is closely related to the orthorhombic marcasite [10] and tetragonal rutile [9]. Our observations confirm a monoclinic crystal system, ...
... prototype arsenopyrite structure and have further implications for studies on ion incorporation into FeAsS structure and its environmental stability and oxidation mechanisms as a source of anthropogenic As release into the environment. Keywords: FeAsS; crystal structure; oxidation; XRPD; TEM ...
... Symmetry and Crystal Structure of the Minerals of the Arsenopyrite Group. Z. Fiir Krist.-Cryst. Mater. 1936, 95, 83–113. [CrossRef] 9. Bindi,L.; Močlo, Y.; Lćone, P.; Suchaud, M. Stoichiometric Arsenopyrite, FeAsS, from La Roche-Balue Quarry, Loire-Atlantique, France: Crystal Structure and Mossbauer ...Ivana Jelić, Aleksandar Pačevski, Aleksandar Kremenović, Aleš Šoster, Andreja Šestan, Janez Zavašnik. "Crystallography and Surface Oxidation of Stoichiometric Arsenopyrite from Šumadija-Kopaonik Pb-Zn/Polymetallic Ore District (Serbia)" in Crystals, MDPI AG (2023). https://doi.org/10.3390/cryst13020278
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A new copper(II) arsenate, Na2Cu3(AsO3OH)4·4H2O containing discrete [Cu3O12]18− units: Synthesis, crystal structure and magnetic properties
Single crystals of the new disodium tricopper(II) tetrakis(hydrogenarsenate(V)) tetrahydrate, Na2Cu3(AsO3OH)4·4H2O were grown under hydrothermal conditions. The compound was characterized by room-temperature single-crystal X-ray diffraction, SEM-EDS analysis, Raman spectroscopy and magnetic susceptibility measurements. Na2Cu3(AsO3OH)4·4H2O represents a new layered structure-type [space group P21/c, a = 8.7089(17), b = 9.7452(19), c = 9.3353(19) Å, β = 92.63(3)°, V = 791.4(3) Å3, Z = 4]. The layers are normal to [100] and are composed of the isolated Cu3O12 units interconnected by AsO3OH coordination ...Na2Cu3(AsO3OH)4•4H2O, хидротермална синтеза, кристална структура, хидрирани хидрокси-арсенати, магнетна својстваTamara Đorđević, Ljiljana Karanović, Zvonko Jagličić. "A new copper(II) arsenate, Na2Cu3(AsO3OH)4·4H2O containing discrete [Cu3O12]18− units: Synthesis, crystal structure and magnetic properties" in Journal of Solid State Chemistry, Elsevier BV (2018). https://doi.org/10.1016/j.jssc.2018.05.024
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Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands
A series of novel ternary Co(II), Ni(II) and Cu(II) complexes containing 2,20-dipyridylamine (dipya), 2,20-bipyridine (bipy), and 1,10-phenanthroline (phen), as aromatic diamine ligands, and dianion of isophthalic acid (ipht) have been prepared by ligand exchange reactions from diluted H2O/EtOH solutions. The complexes were characterized by elemental analysis, IR spectroscopy, magnetic susceptibility measurements and TG and DSC analysis. Three complexes, Cu(dipya)(ipht)H2O (1), Co(dipya)(ipht)2H2O (2) and Cu(ipht)(phen)2H2O (5) are polymeric with bis-monodentate ipht, while the other two complexes M(bipy)(ipht)4H2O, M@Co(II) (3) and ...комплекси прелазних метала, карбоксилатни лиганди, N-лиганди, кристална структура, магнетна својстваJelena Rogan, Dejan Poleti, Ljiljana Karanović, Zvonko Jagličić. "Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands" in Journal of Molecular Structure, Elsevier BV (2011). https://doi.org/10.1016/j.molstruc.2010.11.024
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Low-temperature phase transition and magnetic properties of K3YbSi2O7
Predrag Dabić, Volker Kahlenberg, Biljana Krüger, Marko Rodić, Sabina Kovač, Jovan Blanuša, Zvonko Jagličić, Ljiljana Karanović, Václav Petříček, Aleksandar Kremenović (2021)alkalni silikati elemenata retkih zemalja, fazni prelazi, magnetne karakteristike, razdvajanje kristalnog polja, silikati lantanica... matrix of KF. 2.2. Single-crystal X-ray diffraction measurement, structure solution and refinement Single-crystal XRD data were collected for crystal 1 at ambient conditions (298 K) and at low temperature (100 K). A total of 21 datasets were acquired while cooling crystal 2 from ambient conditions ...
... atomic coordinates of this structural analogue were used as a starting model for structure refinement, where Er was replaced with Yb. The crystal structure was refined to R = 0.013. The structure of the K3YbSi2O7 crystal studied at 100 K (datablock beta_prime- K3YbSi2O7 in the CIF) showed lower Laue ...
... matrix of KF. 2.2. Single-crystal X-ray diffraction measurement, structure solution and refinement Single-crystal XRD data were collected for crystal 1 at ambient conditions (298 K) and at low temperature (100 K). A total of 21 datasets were acquired while cooling crystal 2 from ambient conditions to ...Predrag Dabić, Volker Kahlenberg, Biljana Krüger, Marko Rodić, Sabina Kovač, Jovan Blanuša, Zvonko Jagličić, Ljiljana Karanović, Václav Petříček, Aleksandar Kremenović. "Low-temperature phase transition and magnetic properties of K3YbSi2O7" in Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, International Union of Crystallography (IUCr) (2021). https://doi.org/10.1107/S2052520621006077
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Water in the Alluaudite Type-Compounds: Synthesis, Crystal Structure and Magnetic Properties of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H,□)0.5(H2O,H3O)0.5]2x+
In this study, a new cobalt arsenate belonging to the alluaudite supergroup compounds with the general formula of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H, )0.5(H2O,H3O)0.5]2x+ (denoted as CoAsAllu) was synthesized under hydrothermal conditions. Its crystal structure was determined by a room-temperature single-crystal X-ray diffraction analysis: space group C2/c, a = 11.6978(8), b = 12.5713(7), c = 6.7705(5) Å, b = 113.255(5)◦, V = 914.76(11) Å3, Z = 2 for As6H8Co6O25. It represents a new member of alluaudite-like protonated arsenates and the first alluaudite-like phase ...супергрупа алуаудита, арсенати прелазних метала, хидротермална синтеза, кристална структура, хидратисани хидрокси-арсенати, стехиометрија, магнетна својстваTamara Đorđević, Ljiljana Karanović, Marko Jagodič, Zvonko Jagličić. "Water in the Alluaudite Type-Compounds: Synthesis, Crystal Structure and Magnetic Properties of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H,□)0.5(H2O,H3O)0.5]2x+" in Minerals, MDPI AG (2021). https://doi.org/10.3390/min11121372
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A new polymorph of Ba(AsO3OH): Synthesis, crystal structure and vibrational spectra
Tamara Đorđević, Ljiljana Karanović (2010)A new monoclinic polymorph of Ba(AsO3OH) was synthesized under hydrothermal conditions. It represents a previously unknown structure type. Its crystal structure was determined from a racemic twin using single-crystal X-ray diffraction data collected at 120 and 293 K [space group P21, a=7.2149(14)/7.2370(2), b=7.7028(15)/7.7133(2), c=21.7385(43)/21.8079(5) Å, β=95.95(3)/96.073(1)1, V=1201.6(4)/1210.51(5) Å3, Z=12]. The crystal structure of P21-Ba(AsO3OH) has a layered character and is built up of four types of regularly alternating layers parallel to (0 0 1). Every AsO3OH tetrahedron is chelating to two Ba atoms and ...Ba(AsO3OH), хидротермална синтеза, структурна анализа монокристала, Раманска спектроскопија, инфрацрвена спектроскопија, водоничне везе, хидрогенарсенати земноалкалних металаTamara Đorđević, Ljiljana Karanović. "A new polymorph of Ba(AsO3OH): Synthesis, crystal structure and vibrational spectra" in Journal of Solid State Chemistry, Elsevier BV (2010). https://doi.org/10.1016/j.jssc.2010.09.027
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The role of non-covalent intermolecular interactions on the diversity of crystal packing in supramolecular dihalopyridine–silver(i) nitrate complexes
Sunčica Roca, Lucija Hok, Robert Vianello, Mladen Borovina, Marijana Đaković, Ljiljana Karanović, Dražen Vikić-Topić, Zora Popović (2020)Six novel 1 : 2 complexes of silver(I) nitrate with 2,5-, 2,6- and 3,5-dihalopyridines (halo stands for chlorine and bromine) were prepared by the reaction of an aqueous solution of AgNO3 and the corresponding pyridine derivative in a water–alcohol solution. In spite of having analogous empirical formulae, they reveal intriguing structural differences, except [Ag(NO3)(2,5-Cl2py)2]n (1) and [Ag(NO3)(2,5-Br2py)2]n (4), which are isostructural. In contrast, [Ag(NO3)(3,5-Cl2py)2]2 (3) is dimeric, while its Br analogue [Ag(NO3)(3,5-Br2py)2]n (6) is polymeric in nature, being the ...Sunčica Roca, Lucija Hok, Robert Vianello, Mladen Borovina, Marijana Đaković, Ljiljana Karanović, Dražen Vikić-Topić, Zora Popović. "The role of non-covalent intermolecular interactions on the diversity of crystal packing in supramolecular dihalopyridine–silver(i) nitrate complexes" in CrystEngComm, Royal Society of Chemistry (RSC) (2020). https://doi.org/10.1039/D0CE01257B
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Ionothermal synthesis and crystal structure of a new organic–inorganic hybrid compound:catena-poly[bis(1-ethyl-3-methylimidazolium) [hepta-μ-bromido-pentacuprate(I)]]
A new organic-inorganic hybrid compound, catena-poly[bis(1-ethyl-3-methylimidazolium) [μ5-bromido-tri-μ3-bromido-tri-μ2-bromido-pentacuprate(I)]], {(C6H11N2)2[Cu5Br7]}n, has been obtained under ionothermal conditions from a reaction mixture containing Ba(OH)2•8H O, Cu(OH)2•2H2O, As2O5 , 1-ethyl-3-methylimidazolium bromide and distilled water. The crystal structure consists of complex [Cu5Br7]2- anions arranged in sinusoidal {[Cu5Br7]2-}n chains running along the a axis, which are surrounded by 1-ethyl-3-methylimidazolium cations. Three of the five unique Br atoms and one of the three Cu(I) atoms occupy special positions with half-occupancy (a mirror plane perpendicular to the b ...кристална структура, органско-неорганско хибридно једињење, бакар(I) бромид, јонотермна синтеза, 1-етил-3-метилимидазолијум бромид, Cu•••Cu интеракцијеLjiljana Karanović, Dejan Poleti, Tamara Đorđević. "Ionothermal synthesis and crystal structure of a new organic–inorganic hybrid compound:catena-poly[bis(1-ethyl-3-methylimidazolium) [hepta-μ-bromido-pentacuprate(I)]]" in Acta Crystallographica Section C Structural Chemistry, International Union of Crystallography (IUCr) (2014). https://doi.org/10.1107/S205322961402172X
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Crystal structure of K3EuSi2O7
alkalni silikati elemenata retkih zemalja, kristalna struktura, sinteza metodom fluksa, rendgenska difrakcija na monokristalu... P63/mcm and is isostructural with disilicates K3ErSi2O7 15 and K3YbSi2O7. 22 The crystal structure is comparable to the sorosilicate structure type reported earlier by Vidican and co-authors.13 The crystal structure of the title compound consists of Si2O7 groups and EuO6 polyhedra which form a ...
... Измењено: 2023-11-02 12:24:48 Crystal structure of K3EuSi2O7 Sabina Kovač, Predrag Dabić, Aleksandar Kremenović Дигитални репозиторијум Рударско-геолошког факултета Универзитета у Београду [ДР РГФ] Crystal structure of K3EuSi2O7 | Sabina Kovač, Predrag Dabić, Aleksandar ...
... elements usually crystallize in a structure that contains the rare-earth cation in both a slightly distorted octahedral and an ideal trigonal prismatic coordination environment. Keywords: alkali rare-earth silicates; crystal structure; flux synthesis; single- crystal X-ray diffraction. INTRODUCTION ...Sabina Kovač, Predrag Dabić, Aleksandar Kremenović. "Crystal structure of K3EuSi2O7" in Journal of the Serbian Chemical Society, National Library of Serbia (2021). https://doi.org/10.2298/JSC210218026K
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An update on the mineral-like Sr-containing transition metal arsenates
Tamara Đorđević, Ljiljana Karanović (2021)We report on the crystal structures of three novel synthetic SrM-arsenates (M = Ni and Fe3+), isostructural or structurally related to the minerals from tsumcorite, carminite and brackebuschite groups. They were synthesised under mild hydrothermal conditions and further characterised using single-crystal X-ray diffraction (SXRD), scanning electron microscopy with energy dispersive spectroscopy (SEMEDS) and Raman spectroscopy. SXRD and SEM-EDS yielded formulae: (I) SrNi2(AsO4)2·2H2O, (II) Sr1.4Fe3+ 1.6(AsO4)2(OH)1.6 and (III) SrFe3+(AsO4)(AsO3OH). All three structures are built up of slightly distorted MO6 octahedra ...арсенати метала, кристална структура, дифракција рендгенских зрака на монокристалима, хидротермална синтеза, Раманова спектроскопија, релевантна једињења у животној средини, арсенeochemistry and PetrologyTamara Đorđević, Ljiljana Karanović. "An update on the mineral-like Sr-containing transition metal arsenates" in Mineralogical Magazine, Mineralogical Society (2021). https://doi.org/10.1180/mgm.2021.41
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Temperature induced evolution of nanostructured Ni0.9Zn0.1O
Kremenović Aleksandar, Antić Bratislav, Vučinić-Vasić Milica, Colomban Philippe, Jovalekić Čedomir, Bibić Nataša, Kahlenberg Volker, Leoni Matteo (2010)The crystal structure and microstructure of as-prepared and annealed Ni0.9Zn0.1O were refined at room temperature in both the Fm (3) over barm and R (3) over barm space groups. It is shown that below the Neel point (458 K), where magnetic ordering triggers the presence of a trigonal strain, the common usage of a higher-symmetry non-admissible space group for crystal structure and microstructure analysis via the Rietveld method may result in both an incorrect structure description and incorrect microstructure ...Kremenović Aleksandar, Antić Bratislav, Vučinić-Vasić Milica, Colomban Philippe, Jovalekić Čedomir, Bibić Nataša, Kahlenberg Volker, Leoni Matteo. "Temperature induced evolution of nanostructured Ni0.9Zn0.1O" in Journal of Applied Crystallography no. 43, Denmark: Blackwell Munksgaard (2010). https://doi.org/10.1107/S0021889810019163
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Crystal Structure and Chemical Composition of Ludwigite from Vranovac Ore deposit (Boranja Mountain, Serbia)
Tančić Pavle, Dimitrijević Radovan, Poznanović Maja, Pačevski Aleksandar, Sudar Slobodanka. "Crystal Structure and Chemical Composition of Ludwigite from Vranovac Ore deposit (Boranja Mountain, Serbia)" in Acta Geologica Sinica 86, Beijing:Geological Society of China (2012): 1524-1538
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Crystal-chemistry of the alkaline-earth hydrogen arsenates: crystal structure and vibrational spectraof a new Ba(AsO3OH) polymorphic variety
Đorđević Tamara, Karanović Ljiljana (2010)Đorđević Tamara, Karanović Ljiljana. "Crystal-chemistry of the alkaline-earth hydrogen arsenates: crystal structure and vibrational spectraof a new Ba(AsO3OH) polymorphic variety" in Book of Abstracts, XI General Meeting of the Russian Mineralogical Society combined with Fedorov Session, St. Petersburg, Russia: (2010): 88-89
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Crystal structure of Ba[Co3(OH)2(VO4)2] - Кристална структура Ba[Co3(OH)2(VO4)2]
Đorđević Tamara, Karanović Ljiljana (2011)Đorđević Tamara, Karanović Ljiljana. "Crystal structure of Ba[Co3(OH)2(VO4)2] - Кристална структура Ba[Co3(OH)2(VO4)2]" in XVIII Konferencija Srpskog kristalografskog društva, Izvodi radova, Andrevlje, Srbija:Srpsko kristalografsko društvo (2011): 60-61
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Crystal structure of Cd5(VO4)2(OH)4 and CdV3O7 - Кристалне структуре Cd5(VO4)2(OH)4 и CdV3O7.
Đorđević Tamara, Karanović Ljiljana (2013)Đorđević Tamara, Karanović Ljiljana. "Crystal structure of Cd5(VO4)2(OH)4 and CdV3O7 - Кристалне структуре Cd5(VO4)2(OH)4 и CdV3O7." in XX Konferencija Srpskog kristalografskog društva, Izvodi radova, Avala, Srbija:Srpsko kristalografsko društvo (2013): 64-65
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Defect detection in aluminium using pulse thermography for sample width periodic structure
Damnjanović Vesna, Goran Dikić, B. Milanović and Slobodan Petričević. "Defect detection in aluminium using pulse thermography for sample width periodic structure" in FOTONIKA 2017, VI International School and Conference on Photonics, Beograd, Srbija:Institute of Physics Belgrade (2017): 82
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Shallow-landslide spatial structure interpretation using a multi-geophysical approach
Ristić Aleksandar, Abolmasov Biljana, Govedarica Miro, Petrovački Dušan, Ristić Aleksandra. "Shallow-landslide spatial structure interpretation using a multi-geophysical approach" in Acta Geotechnica Slovenica 9 no. 1, Ljubljana, Slovenia:University of Maribor, University of Ljubljana, Slovenian Geotechnical Society (2012): 47-59