Претрага
5 items
-
Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species
Biljana P Dojčinović, Boštjan Jančar, Lotfi Bessais, Aleksandar Kremenović, Nataša P Jović-Jovičić, Predrag T Banković, Dalibor M Stanković, Miloš Ognjanović, Bratislav V Antić (2019)Herein we report effects of partial substitution of Fe3+ by Y3+ in magnetite (Fe3O4) on morphology and inorganic arsenic species adsorption efficiency of the Fe3−xYxO4 nanoparticles formed. The series of Fe3−xYxO4 (x=0.00, 0.042 and 0.084, labeled as Y00, Y05 and Y10, respectively) was synthesized using co-precipitation followed by microwave-hydrothermal treatment (MW) at 200°C. With increase of yttrium content(xvalue), both the morphological inhomogeneity of the samples and the fraction of spinel nanorods as compared to spinel pseudospherical particles increased. By ...Biljana P Dojčinović, Boštjan Jančar, Lotfi Bessais, Aleksandar Kremenović, Nataša P Jović-Jovičić, Predrag T Banković, Dalibor M Stanković, Miloš Ognjanović, Bratislav V Antić. "Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species" in Nanotechnology, IOP Publishing (2019). https://doi.org/10.1088/1361-6528/ab3ca2
-
Some examples of interactions between certain rare earth elements and soil
... solution following adsorption, whereby the distribution between the liquid and solid phase of adsorption solution for different concentrations is presented. Most often by adsorption isotherms the information on adsorption intensity, adsorbed quantity as well as on maximum adsorption capacity of the ...
... of the most frequently used adsorption isotherms is the Freundlich (H. Freundlich) isotherm. Freundlich isotherm is used for describing the physical adsorption, being the consequence of the Van der Waals forces impact, it is reversible and there may come to adsorption of adsorbents in a number of ...
... the metallic ion adsorbed mass per mass of adsorbent on the equilibrium concentration of that ion in the solution- Freundlich adsorption isotherm. Parameters for adsorption intensity (n) and Freundlich isotherm constant (kf) are determined in the equation of the line, according to the equation (3) ...Zlatko Nikolovski, Jelena Isailović, Dejan Jeremić, Sabina Kovač, Ilija Brčeski. "Some examples of interactions between certain rare earth elements and soil" in Journal of the Serbian Chemical Society, National Library of Serbia (2021). https://doi.org/10.2298/JSC211006095N
-
Interaction of sodium dodecylsulfate (SDS) with homoionic montmorillonites: adsorption isotherms and metal-ion release
The interaction of dodecylsulfate anions (DS−) with homoionic Ca-, Mg-, Ni-, Cu-, Cd-, Pb- and Fe-montmorillonites were investigated. Mg- and Cd-montmorillonite do not adsorb DS−, and an anion exchange at the edges of the clay mineral does not take place. Three different adsorption processes are identified on the other montmorillonites: i) Fe-montmorillonite is covered with amorphous iron hydroxide, and DS−-anions are bound at positively charged sites. ii) On Ca- and Pb-montmorillonite DS− is precipitated as Me(DS)2. iii) On Ni- ...M. Ilic, J. Gonzalez, A. Pohlmeier, H. D. Narres, M. J. Schwuger. "Interaction of sodium dodecylsulfate (SDS) with homoionic montmorillonites: adsorption isotherms and metal-ion release" in Colloid Polymer Science, Springer Science and Business Media LLC (1996). https://doi.org/10.1007/BF00656626
-
Adsorption and degradation of some psychiatric drugs by sol-gel synthesized titania-based photocatalysts: influence of tungsten and sodium content
Nina L. Finčur, Maja J. Šćepanović, Mirjana Grujić-Brojčin, Biljana F. Abramović, Jugoslav B. Krstić, Aleksandar Kremenović, Tatjana Srećković, Aleksandar Golubović (2019)Mesoporous anatase nanopowders were doped with 0.05−0.5 mol% of W6, in order to obtain more efficient photocatalyst than TiO2 Degussa P25 in the degradation of amitriptyline (AMI) under simulated solar irradiation (SSI). Dominant XRPD peaks were ascribed to anatase phase, with additional peaks which could correspond to brookite, TiO2 bronze and sodium titanate, Na2Ti9O19. The Raman scattering measurements have confirmed anatase as dominant phase, with broad Raman feature at ~270 cm−1 possibly related to Ti–O–Na stretching vibration. All W-doped ...Sol-gel synthesis, Doped titania nanopowders, XRPD, Raman spectroscopy, Adsorption and photocatalytic degradation, Psychiatric drugsNina L. Finčur, Maja J. Šćepanović, Mirjana Grujić-Brojčin, Biljana F. Abramović, Jugoslav B. Krstić, Aleksandar Kremenović, Tatjana Srećković, Aleksandar Golubović. "Adsorption and degradation of some psychiatric drugs by sol-gel synthesized titania-based photocatalysts: influence of tungsten and sodium content" in Journal of Sol-Gel Science and Technology, Springer Science and Business Media LLC (2019). https://doi.org/10.1007/s10971-019-04925-4
-
Adsorption and Polymerization of Aniline on Cu(II)-Montmorillonite: Vibrational Spectroscopy and ab Initio Calculation
Batch adsorption experiments in the presence of oxygen were performed to study the interlayer reactions of aniline on Cu(II)-montmorillonite in aqueous solutions. At concentrations below a critical value of CC ) 2.6 mmol dm-3 only a colored Cu(II)-aniline complex is formed, characterized by a stability constant of log(Kassoc/dm3 mol-1) ) 1.5. At concentrations beyond Cc aniline polymerizes yielding a dark brown product, which is identified by two vibrational spectroscopy techniques, attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy and ...M. Ilić, E. Koglin, A. Pohlmeier, H. D. Narres, M. J. Schwuger. "Adsorption and Polymerization of Aniline on Cu(II)-Montmorillonite: Vibrational Spectroscopy and ab Initio Calculation" in Langmuir (2000). https://doi.org/ 10.1021/la000534d