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Упит dcterms_subject_txt:Ru(II)

519 items

  • Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles

    Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović (2013)
    Kinetika i mehanizam reakcija supstitucije između [Ru(trpi)(bpi)Cl]+ sa nukleofilima gvanozin-5′-monofosfatom, L-histidinom, tioureom i dimetilsulfoksidom proučavani su spektrofotometrijski u 0,1 M NaClO4 na 310 K. Red reaktivnosti za odabrane ligande je: tiourea > gvanozin-5′-monofosfat > L-histidin > DMSO. Ovaj red je povezan sa elektronskim, strukturnim i hemijskim karakteristikama kompleksa i nukleofila. Reakcija supstitucije sa tioureom je proučavana na tri različite temperature (288, 298 i 310 K). Negativna entropija aktivacije DS = potvrđuje asocijativni način aktivacije. Formiranje kompleksa [Ru(trpi)(bpi)H2O]2+ sa ligandima ...
    Kinetika, Ravnoteža, Ru(II), L-Histidin, Guanozin-5' -monofosfat, Dimetilsulfoksid, Tiourea
    ... activity were the chlorido-ammine complexes fac- [Ru(NH3)3Cl3] and cis-[Ru(NH3)4Cl2] [11]. However, although active, these compoundswere not soluble enough for pharmaceutical use [6, 7]. In the following years, a large number of different Ru(II) and Ru(III) compounds were studied for their cytotoxic ...
    ... activated by hydrolysis, mainly of the chlorido ligands. After hydroly- sis, the reduction of Ru(III) to Ru(II) complex occurs because cells contain different amounts of reducing agents [23–25]. Finally, the Ru(II) complex formed reacts with the DNA molecule, binding preferentially to guanine residues ...
    ... and the well-known coordination to metal ions via N7 atoms, this nucleotide could be bound to Ru(II) via phosphate oxygen atoms as well. This kind of coordination has been already published for some Ru(II) complexes [9, 26]. After formation of an adduct where the metal ion is coordinated to oxygen ...

  • Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands

    Jelena Rogan, Dejan Poleti, Ljiljana Karanović, Zvonko Jagličić (2011)
    A series of novel ternary Co(II), Ni(II) and Cu(II) complexes containing 2,20-dipyridylamine (dipya), 2,20-bipyridine (bipy), and 1,10-phenanthroline (phen), as aromatic diamine ligands, and dianion of isophthalic acid (ipht) have been prepared by ligand exchange reactions from diluted H2O/EtOH solutions. The complexes were characterized by elemental analysis, IR spectroscopy, magnetic susceptibility measurements and TG and DSC analysis. Three complexes, Cu(dipya)(ipht)H2O (1), Co(dipya)(ipht)2H2O (2) and Cu(ipht)(phen)2H2O (5) are polymeric with bis-monodentate ipht, while the other two complexes M(bipy)(ipht)4H2O, M@Co(II) (3) and ...
    комплекси прелазних метала, карбоксилатни лиганди, N-лиганди, кристална структура, магнетна својства

  • Synthesis of MnCo2O4 nanoparticles as modifiers for simultaneous determination of Pb(II) and Cd(II)

    Vesna Antunović, Marija Ilić, Rada Baošić, Dijana Jelić, Aleksandar Lolić (2019)
    The porous spinel oxide nanoparticles, MnCo2O4, were synthesized by citrate gel combustion technique. Morphology, crystallinity and Co/Mn content of modified electrode was characterized and determined by Fourier transform infra-red spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray diffraction pattern analysis (XRD), simultaneous thermogravimetry and differential thermal analysis (TG/DTA). Nanoparticles were used for modification of glassy carbon electrode (GCE) and new sensor was applied for simultaneous determination of Pb(II) and Cd(II) ions in water samples with the ...
    MnCo2O4 nanočestice, modifikatori, određivanje Pb (II) and Cd(II)

  • Supstitucione reakcije Pd(II) kompleksa sa biološki važnim biomolekulima

    Aleksandar M. Mijatović, Jovana Bogojeski (2017)
    Kompleksi Pd(II), supstitucione reakcije

  • Distribution of major and trace elements in the Kovin lignite (Serbia)

    Dragana Životić, Olga Cvetković, Predrag Vulić, Ivan Gržetić, Vladimir Simić, Konstantin Ilijević, Biljana Dojčinović, Suzana Erić, Bogdan Radić, Sanja Stojadinović, Snežana Trifunović (2019)
    geochemical and mineralogical study was performed on lignite samples from the Upper Miocene Kovin deposit, hosting three coal seams. The Kovin lignite is characterized by high moisture content, medium to high ash yield, medium to high sulphur content and a relatively low gross and net calorific value. The mineralogical composition, and major and trace element contents were determined by X-ray diffraction, scanning electron microscopy with energy dispersive Xray spectroscopy (SEM-EDS) analyses, and inductively coupled plasma optical emission spectrometry (ICP-OES). ...
    General Earth and Planetary Sciences, General Environmental Science
    ... XC 21 I 30/91 26.35–27.65 MC 22 I 31/91 27.65–28.15 MMiC 23 II 33/91 45.00–45.60 MXC 24 II 34/91 45.60–46.05 XC 25 II 36/91 47.05–48.35 MMiC 26 II 37/91 48.60–49.30 MXC 27 II 38/91 49.30–49.50 XC 28 II 39/91 50.60–50.90 MMiC 29 II 40/91 51.60–52.85 MC 30 GD-601 A I (Ia) 42/601 42.65–43.10 XC ...
    ... 33/91 II 43.54 11.70 35.95 1.46 37.97 24.3 23.3 34/91 II 49.65 4.26 21.74 1.65 45.34 25.9 24.8 36/91 II 32.66 4.02 56.11 1.35 28.08 21.2 19.9 37/91 II 51.59 11.60 16.47 3.12 48.33 25.6 24.6 38/91 II 51.62 7.16 16.38 0.80 46.09 25.5 24.4 39/91 II 43.01 10.05 37.05 1.00 36.69 24.4 23.3 40/91 II 42.59 ...
    ... 31/91 I n.a n.a n.a n.a n.a n.a 33/91 II 47.7 28.3 12.4 4.3 3.5 3.9 34/91 II 47.8 15.9 24.6 2.6 6.1 3.1 36/91 II 53.8 27.5 9.3 4.1 3.4 1.9 37/91 II 19.9 8.6 50.7 0.8 19.6 0.4 38/91 II 25.0 30.4 12.1 12.0 0.3 20.3 39/91 II 40.2 37.2 9.4 8.3 1.7 3.3 40/91 II 63.2 15.1 9.9 8.7 0 3.3 42/601 I (Ia) ...

  • Cytotoxic activity of tetradentate Schiff Base Copper(II) complexes

    Nevenka Gligorijević, Aleksandar Mijatović, Sandra Aranđelović, Rada Baošić (2021)
    Istraživanje kompleksa bakra kao potencijalnih antikancerogenih agenasa nudi ohrabrujuće perspektive u odnosu na komplekse platine (II) računajući na smanjenu toksičnost, novi mehanizam delovanja, različit spektar aktivnosti i perspektivu neunakrsne rezistencije. Kompleksi Šifovih baza bakra(II) koji sadrže tetradentatne ligande acac2en tipa (acac2en (1); tfacac2en (3), acactfacacen (4), acacphacacen (6)) pokazali su važnu antioksidativnu aktivnost, visok potencijal za interakciju sa HSA i DNK, u prethodnim studijama. Zbog toga je bilo interesantno ispitati i uporediti potencijal antikancerogene aktivnosti in vitro, u odnosu ...
    Bakar(II) kompleksi, citotoksičnost, ćelijski ciklus

  • Adsorption and Polymerization of Aniline on Cu(II)-Montmorillonite:  Vibrational Spectroscopy and ab Initio Calculation

    M. Ilić, E. Koglin, A. Pohlmeier, H. D. Narres, M. J. Schwuger (2000)
    Batch adsorption experiments in the presence of oxygen were performed to study the interlayer reactions of aniline on Cu(II)-montmorillonite in aqueous solutions. At concentrations below a critical value of CC ) 2.6 mmol dm-3 only a colored Cu(II)-aniline complex is formed, characterized by a stability constant of log(Kassoc/dm3 mol-1) ) 1.5. At concentrations beyond Cc aniline polymerizes yielding a dark brown product, which is identified by two vibrational spectroscopy techniques, attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy and ...
    Анилин, адсорпција, полимеризација, Cu(II)-Монтморилонит, ФТИР, аб инитио прорачун

  • Antioxidant and antimicrobial activity of some tetradentate Schiff bases and their Cu (II) complexes

    Aleksandar Mijatović, Milan Nikolić, Snežana Spasić, Aleksandra N. Žerađanin, Kristina Joksimović, Aleksandar Lolić, Rada Baošić (2020)
    Šifove baze i njihovi Cu(II) kompleksi su poznati po svojoj biološkoj aktivnosti. U ovom radu proučavana je antibakterijska aktivnost protiv gram-negativnih sojeva Escherichia coli, Pseudomonas aeruginosa i Staphilococcus piogenes, kao i Gram-pozitivnih Staphilococcus piogenes i Pseudomonas aeruginosa, zajedno sa antifungalnim dejstvom protiv Musperg strainilusa, A. Takođe, tehnički jednostavni i brzi testovi kao što su ABTS, HORAC i ORAC korišćeni su za ispitivanje antioksidativne aktivnosti kako bi se uporedili dobijeni rezultati sa različitim tipovima testova. Uprkos tome što je princip ...

  • The interaction of organoselenium trans-palladium(II) complexes toward small-biomolecules and CT-DNA

    Vera M. Divac, Aleksandar Mijatović, Marina D. Kostić, Jovana Bogojeski (2017)
    Serija organoselenijum trans-paladijum(II) kompleksa 1 (bis(2-(fenilselanilmetil)oksolan)dihloropaladijum(II)), 2 (bis(2-(fenilselanilmetil)oksan)dihloropaladijum(II)) i 3 (bis(2) ,2-dimetil-3-(fenilselanil)oksan)dihloropaladijum(II)) su korišćeni za ispitivanje reaktivnosti ovog specifičnog tipa kompleksa prema različitim bio-molekulima. Ovaj sistem je od posebnog interesa jer se jako malo zna o supstitucionim reakcijam organoselenijum paladijum(II) kompleksa sa trans konfiguracijom. Zamena koordinovanog hlorida sa serijom malih bio-molekula (l-Met, l-His, l-Cis, GSH i 5′-GMP) proučavana je pod uslovima pseudo-prvog reda kao funkcija koncentracije nukleofila i temperature korišćenjem tehnika zaustavljenog toka. Rezultati za proučavane komplekse ukazuju da ...
    Pd(II), Selen, Substitucija, Kinetika, Mehanizam

  • Barium nickel(II) diarsenate, BaNiAs2O7 - Баријум-бакар(II)-диарсенат, BaNiAs2O7

    Kovač Sabina, Karanović Ljiljana, Wittwer Astrid, Đorđević Tamara (2014)

  • Kinetics and the mechanism of the supstitution reactions of some Pt(II) and Pd(II) complexes

    Bogojeski Jovana, Mijatović Aleksandar, Đurović Mirjana, Petrović Biljana, Bugarčić D. Živadin (2011)

  • DNA/BSA interactions and cytotoxic studies of tetradentate N,N,O,O Schiff base copper(II) complexes

    Aleksandar Mijatović, Angelina Caković, Aleksandar Lolić, Snezana Sretenović, Marko Živanović, Dragana Seklić, Jovana Bogojeski, Biljana Petrović (2023)
    Three Schiff base Cu(II) complexes, (N,N’-bis(acetylacetone)propylenediimine)copper(II) complex, [Cu(acac2pn)] (1), (N,N'-bis-(benzoylacetone)propylenediimine)copper(II) complex, [Cu(phacac2pn)] (2) and (N,N’-bis-(trifluoroacetylacetone)propylenediimine)copper(II) complex, [Cu(tfacac2pn)] (3), were used to investigate the interactions with calf thymus DNA (ct-DNA) and bovine serum albumin (BSA) using the electronic absorption and spectroscopic fluorescence methods. UV-Vis absorption studies showed that studied complexes interact with DNA molecule and exhibit moderate binding affinity. Fluorescence studies of complexes 1-3 also showed a possibility for DNA intercalation as well as a relatively high binding ability ...
    General Chemistry

  • Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes

    Aleksandar Mijatović, Jovana Bogojeski, Biljana Petrović, Živadin D. Bugarčić (2011)
    Reakcije supstitucije monofunkcionalnih kompleksa [(TLtBu)PdCl]+ i [Pd(tpdm)Cl]+, gde je TLtBu = 2,6-bis[(1,3-di-terc-butilimidazolin-2-imino)metil]piridin i tpdm = terpiridindimetan, sa nukleofilima kao što su: tiourea, I−, Br−, NO2−, piridin i dimetil-sulfoksid (DMSO) proučavani su u 0,1 M vodenom rastvoru NaClO4 u prisustvu 10 mM NaCl. Reakcije su sprovedene na tri različite temperature (288, 298 i 308 K) korišćenjem tehnike zaustavljenog protoka na različitim temperaturama. Reakcije supstitucije su praćene pod uslovima pseudo prvog reda sa velikim viškom nukleofila. Dobijeni rezultati pokazuju da kompleks ...
    Materials Chemistry, Inorganic Chemistry, Physical and Theoretical Chemistry
    ... for the substitution reactions of the Pd(II) complexes. Comparing the reactivity of the nucleophiles we observed that the reactivity decreases in the following order: thiourea > I� > Br� > NO2 � > pyridine > DMSO. It is generally known that the Pt(II) and Pd(II) complexes have a very high affinity towards ...
    ... for the substitution reactions of the Pd(II) complexes. Comparing the reactivity of the nucleophiles we observed that the reactivity decreases in the following order: thiourea > I” > Br- > NO” > pyridine > DMSO. It is generally known that the Pt(II) and Pd(II) complexes have a very high affinity towards ...
    ... hindered monofunctional Pd(II) complexes Aleksandar Mijatović, Jovana Bogojeski, Biljana Petrović, Živadin D. Bugarčić Дигитални репозиторијум Рударско-геолошког факултета Универзитета у Београду [ДР РГФ] Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes | Aleksandar ...

  • Грешка инклинације код депозиционе реманетне магнетизације

    Mirko Petković, Vesna Cvetkov (2019)
    ... available in open access, as well as the employees' publications. - The Repository is available at: www.dr.rgf.bg.ac.rs II KONGRES GEOLOGA BOSNE I HERCEGOVINE SA MEĐUNARODNIM UČEŠĆEM II КОНГРЕС ГЕОЛОГА БОСНЕ И ХЕРЦЕГОВИНЕ СА МЕЂУНАРОДНИМ УЧЕШЋЕМ 314 GREŠKA INKLINACIJE KOD DEPOZICIONE REMANENTNE ...
    ... elipticiteta zrna, f, zavisnog od mjerenih vrijednosti anizotropije anhisterezisne remanentne magnetizacije uzorka. II KONGRES GEOLOGA BOSNE I HERCEGOVINE SA MEĐUNARODNIM UČEŠĆEM II КОНГРЕС ГЕОЛОГА БОСНЕ И ХЕРЦЕГОВИНЕ СА МЕЂУНАРОДНИМ УЧЕШЋЕМ 315 Presječna tačka y-ose i prave koja najbolje aproksimira ...
    ... factor, f, which is dependent on the measured values of the anisotropy of anhysteretic remanent magnetization is II KONGRES GEOLOGA BOSNE I HERCEGOVINE SA MEĐUNARODNIM UČEŠĆEM II КОНГРЕС ГЕОЛОГА БОСНЕ И ХЕРЦЕГОВИНЕ СА МЕЂУНАРОДНИМ УЧЕШЋЕМ 316 calculated. The intersection point of the y-axis ...

  • Heavy metals in lignite and soil of Kostolac-Kovin coal basin, eastern Serbia - comparative analysis with selected cities in Serbia, region, Europe and world

    Bogoljub Vučković, Bojan Dimitrijević (2023)
    The Kostolac-Kovin coal basin with an area of 320 km2, with 5 separate layers of coal and with a total of about 5.7 Bt of geological resources and reserves represents an exceptional potential for coal production in Serbia. The coal resources listed in this way are not fully exploitable, but they represent potential for consideration. In this paper, we deal with the geochemical characteristics of coal seams and perform a comparative analysis of coal affectation on the environment. With ...
    lignite, heavy metals, concentrations
    ... GER ATBOTTOM: Forest, FRA Murcia, ESP Oslo, NOR Galway, IRL Moscow 3,RU Figure 8. Presentation of the content of Zn, Pb and Cu in the urban and recreational top soil in the cities ofthe Furope; yellow – I, H and II Kostolac coal, black - the most polluted soil Figure 8 shows that the contents ...
    ... in the excavation phase are some parts of 1, II and III layers (I and II layers in Kovin by underwater exploitation; II and III layers in the Drmno surface mine Figure 2); 3. Inthe excavation plan are all remaining parts of Ia, I and II layer (Ia, I and II layers at the future surface mine West Kostolac ...
    ... ppm - Europe Cities Top Soil VS. Kostolac Coal Year, early 2023. ToPFVE ATBOTTOM: Targoviste,RO — Murcia,ESP fceWi Ws - BaiaMare,RO _ Moscow 3,RU BaMare,RO - Moscow3,HU ” | Coal, SER Glpow,SCO — M a\ StR -T _ondon, Forest, FRA < Naples,TA MI Coal, SER London,Uk Fa rlin, lI Coal, SER: Hamburg ...

  • A series of nickel(ii) thiocyanate complexes comprising various molar contents of isonicotinamide and water as ligands or co-crystallized moieties – an experimental and computational study

    Lucija Hok, Robert Vianello, Dubravka Matković-Čalogović, Ljiljana Karanović, Sunčica Roca, Jarosław Jaźwiński, Marina Tašner, Darko Vušak, Marijana Đaković, Zora Popović (2022)
    oktaedarski kompleksi Ni(II), izonikotinamid, tiocijanatni anjon

  • Eksploatacioni učinci ugljenih sistema na površinskom kopu Tamnava–Zapadno polje

    Marko Lazić, Filip Miletić, Milena Lekić, Veljko Rupar, Željko Petrović, Lazar Žujović (2021)
    U radu su analizirani eksploatacioni učinci ugljenih sistema na površinskom kopu Tamnava–Zapadno polje. Period analize je prvih šest meseci tekuće godine. Analiza je vršena sa aspekta ostvarene proizvodnje, kvaliteta uglja, efektivnog vremena rada, kapacitetnog i vremenskog iskoršćenja i zastoja sistema. Za poređenje podataka različitih parametara koji po svojoj prirodi nisu međusobno uporedivi, u radu su korišćene metode višekriterijumskog odlučivanja.
    proizvodnja uglja, zastoji, metode višekriterijumskog odlučivanja
    ... ||,,...,..., ijijjn MAXMIN AvjKivjKvvvv ii + æöæö =ÎÎ= ç÷ç÷ èøèø 2 1 () n ijj j Sivv ++ = =- å { } ''' 12 ||,,...,..., ijijjn MINMAX AvjKivjKvvvv ii - æöæö =ÎÎ= ç÷ç÷ èøèø 2 1 () n ijj j Sivv -- = =- å 1 , 00 i i ii S CC SS - -+ =££ + ...
    ... Sistem Sj Rj I BTD 0,31 0,00 II BTD 0,00 1,00 III BTD 1,00 1,00 IV BTD 0,49 0,00 Tabela 4.2 Vrednosti Qj za v = 0,5; 0,6 i 0,7 Sistem v = 0,5 v = 0,6 v = 0,7 Qj Rang Qj Rang Qj Rang I BTD 0,153015 1 0,183619 1 0,214222 1 II BTD 0,5 3 0,4 3 0,3 2 III BTD ...
    ... m nnnnm Axxx Axxx M Axxx éù êú êú = êú êú ëû MMMMM * max min iij j iij j xx xx - = = * * 1 * * () () () max () n iij ji i ii iij ji i ii xx Sw xx xx Rw xx - = - - = å - éù - = êú - êú ëû ** () () (1) ()() j j ss RjR Qvv ssRR - - -- - - =+- -- * * min;max min;max ...

  • The influence of structural modification of Pd(II) pincer-type complexes on the kinetics of substitution reactions

    Snežana Jovanović Stević, Snežana Radisavljević, Aleksandar Mijatović, Biljana Petrović, Ana Kesić (2023)
    This mini-review summarizes the kinetic data obtained for the substitution reactions of some palladium(II) complexes containing bis-pyrazolylpyridine derivatives as pincer-type ligands with biologically significant nitrogen- and sulfur-donor biomolecules as nucleophiles. Three structurally different palladium(II) complexes were selected: [Pd(L1)Cl]+ (Pd1), [Pd(L2)Cl]+ (Pd2) and [Pd(L3)Cl]+ (Pd3) (where L1 = bis(2-(1H-pyrazol-1-yl)ethyl)amine, L2 = 2,6-bis(5-(tert-butyl)-1H-pyrazol-3-yl)pyridine, and L3 = 2,6-bis(5-(tert-butyl)-1-methyl-1H-pyrazol-3-yl)pyridine, while for the entering nucleophiles were used thiourea (Tu), L-methionine (L-met), and guanosine-5’-monophosphate (5’-GMP). Kinetic measurements were carried out for all systems as pseudo-first ...

  • Производња и одржавање рударске опреме на примеру предузећа Колубара метал

    Вања Миловановић (2024)
    У раду је извршено пројектовање технолошког процеса израде вратила на стругу. Кроз теоријску анализу, дати су основни постулати обраде стругањем, стругови као машине алатке, врсте стругова, начини стругања и примењени алати. У практичном делу, дефинисани су редоследи операција и захвата, режими обраде, изабрана машина алатка и алати за све захвате и одређено укупно време обраде потребно да се направи финални производ. Вратило из студије случаја представља компоненту редуктора погона за копање роторног багера SRs.1200.24/4+VR.
    производно машинство, обрада метала резањем, израда вратила на стругу

  • Equilibrium and kinetic studies of the reactions between [Ru(terpy)(bipy)Cl]Cl complex and biologically important N-donor ligands

    Aleksandar Mijatović, Biljana Petrović, Ratomir Jelić, Živadin Bugarčić (2011)
    Studije u oblasti antikancerogenih karakteristika jedinjenja rutenijuma(III/II) izazivaju veliku pažnju već nekoliko godina otkako su neka od njih kao što su KP1019 (indazolijum-tetrahloridobis(H-indazol)rutenat(III)) i NAMI-A (imidazolijum) -trans-tetrahlorido(dimetilsulfoksid)indazolerutenat(III)) dostigao nivo kliničkog ispitivanja. Kompleksi rutenijuma u ​​reakciji sa molekulom DNK formiraju prvenstveno gvanin- i adenin-adukt, kao komplekse platine. Takođe, nekoliko studija ukazuje na veoma jake interakcije sa proteinima. Međutim, kompleksi Ru(III/II) pokazuju generalno manje toksične efekte od lekova platine(II).1 Proučavali smo kinetiku reakcija supstitucije kompleksa [Ru(terpi)(bipi)Cl]Cl sa biološki važnim ligandima: dimetilsulfoksidom, gvanozin-5’-monofosfatom, ...