Претрага
3 items
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Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles
Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović (2013)Kinetika i mehanizam reakcija supstitucije između [Ru(trpi)(bpi)Cl]+ sa nukleofilima gvanozin-5′-monofosfatom, L-histidinom, tioureom i dimetilsulfoksidom proučavani su spektrofotometrijski u 0,1 M NaClO4 na 310 K. Red reaktivnosti za odabrane ligande je: tiourea > gvanozin-5′-monofosfat > L-histidin > DMSO. Ovaj red je povezan sa elektronskim, strukturnim i hemijskim karakteristikama kompleksa i nukleofila. Reakcija supstitucije sa tioureom je proučavana na tri različite temperature (288, 298 i 310 K). Negativna entropija aktivacije DS = potvrđuje asocijativni način aktivacije. Formiranje kompleksa [Ru(trpi)(bpi)H2O]2+ sa ligandima ...... potentiometric and spectrophotometric measurements. Complex formation of [Ru(trpy)(bpy)H>O]°* with HL (where HL = 5'-GMP or t-His) The complex formation of [Ru(trpy)(bpy)H,O]?* with ligands 5’-GMP or L-His, symbolized by HL, was studied Table 2 Stability constants of [Ru(trpy)(bpy)H2O] 2?–HL complexes ...
... titration giving [Ru(trpy)(bpy)(HL)]2? (HL = 50-GMP) complex with the maximum in concentration at a pH of about 5. The complex with deprotoneted nucleotide [Ru(trpy)(bpy)(L)]? starts to form at pH 5, and its maximum in concentration is reached at a pH of about 8.5. The pure hydrolytic com- plexes of [ ...
... analogs and their several side effects have stimulated the search for other metal-based anticancer drugs with metal ions differ- ent from platinum [4, 5]. Ruthenium complexes are today the most promising compounds for the investigation of antitumor activity of metal-containing pharmaceuticals [6–10] ...Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović. "Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles" in Monatshefte für Chemie - Chemical Monthly, Springer Science and Business Media LLC (2013). https://doi.org/10.1007/s00706-013-1044-1
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Neanderthal Settlement of the Central Balkans during MIS 5: Evidence from Pešturina Cave, Serbia
Dušan Mihailović, Stefan Milošević, Bonnie A.B. Blackwell, Norbert Mercier, Susan M. Mentzer, Christopher E. Miller, Mike W. Morley, Katarina Bogićević, Dragana Đurić, Jelena Marković, Bojana Mihailović, Sofija Dragosavac, Senka Plavšić, Anne R. Skinner, Iffath I.C. Chaity, Yiwen E.W. Huang, Seimi Chu, Draženko Nenadić, Predrag Radović, Joshua Lindal, Mirjana Roksandić (2022)Recent research in the southern Central Balkans has resulted in the discovery of the first Middle Paleolithic sites in this region. Systematic excavations of Velika and Mala Balanica, and Peˇsturina (southern Serbia) revealed assemblages of Middle Paleolithic artifacts associated with hominin fossils and animal bones. This paper focuses on Pesturina Layer 4, radiometrically and biostratigraphically dated to Marine Isotope Stage (MIS) 5, which yielded traces of temporary hunting camps. The remains of large ungulate prey are associated with predominantly ...Dušan Mihailović, Stefan Milošević, Bonnie A.B. Blackwell, Norbert Mercier, Susan M. Mentzer, Christopher E. Miller, Mike W. Morley, Katarina Bogićević, Dragana Đurić, Jelena Marković, Bojana Mihailović, Sofija Dragosavac, Senka Plavšić, Anne R. Skinner, Iffath I.C. Chaity, Yiwen E.W. Huang, Seimi Chu, Draženko Nenadić, Predrag Radović, Joshua Lindal, Mirjana Roksandić. "Neanderthal Settlement of the Central Balkans during MIS 5: Evidence from Pešturina Cave, Serbia" in Quaternary International (2022)
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New paleoecological perspectives on Late Pleistocene Neanderthals in northern Balkans: the rodent assemblages from Smolućka cave (Serbia)
Mihailo Jovanović, Katarina Bogićević, Draženko Nenadić, Jordi Agustí,·Christian Sánchez Bandera, Juan Manuel López García, Hugues Alexandre Blain (2022)During the Late Pleistocene, the Balkans came to be an important region with many isolated areas, enabling fauna, alongside Neanderthals, to thrive in the area. This work is focused on paleoenvironmental and paleoclimatic changes that occurred in the northern Balkan Peninsula with a special focus on fossil record from Smolućka cave aging from MIS 5 to MIS 3. Based on available data, an attempt has been made to establish a synthetic chronological context for the faunal assemblages recovered from ...Mihailo Jovanović, Katarina Bogićević, Draženko Nenadić, Jordi Agustí,·Christian Sánchez Bandera, Juan Manuel López García, Hugues Alexandre Blain. "New paleoecological perspectives on Late Pleistocene Neanderthals in northern Balkans: the rodent assemblages from Smolućka cave (Serbia)" in Archaeological and Anthropological Sciences (2022)