Претрага
3 items
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Microemulsion with aromatic oil as cleaner media for electropolymerisation
Abstract Microemulsion polymerization is widely used as a cleaner alternative way to prepare intrinsically conductive polymers. We studied isothermal phase diagrams for microemulsions of the electropolymerizable heterocyclic aromatic oil 3,4-ethylenedioxythiophene (EDOT), aqueous LiClO4 solution and alkyl polyethoxylate. Our specific goal was to assess the effect of LiClO4 salt on the phase behaviour. The phase behaviour was characterized by stepwise titration and microscopic analyses. Here we found that the increase of the concentration of LiClO4 salt shifts the microemulsion region ...M. Ilić, F.-H. Haegel, S. Zlatanovic, N. Potkonjak, B. Simonovic. "Microemulsion with aromatic oil as cleaner media for electropolymerisation" in Environmental Chemistry Letters, Springer Science and Business Media LLC (2005). https://doi.org/10.1007/s10311-005-0101-3
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The influence of alkyl polyglucosides (and highly ethoxylated alcohol boosters) on the phase behavior of a water/toluene/technical alkyl polyethoxylate microemulsion system
Marija Ilic, Franz-Hubert Haegel, Vesna Pavelkic, Dragan Zlatanovic, Snezana Nikolic-Mandic, Aleksandar Lolic, Zoran Nedic (2016)The influence of additives (alkyl polyglucoside, Glucopon 600 CS UP and alcohol ethoxylate C18E100) on the behavior of the water/toluene/Lutensol ON 50 (technical oxoalcohol, i-C10E5) microemulsion system as a function of temperature and composition has been investigated. The phase behavior of the microemulsions was determined by vertical sections through the Gibbs phase prism (fish-like phase diagrams). Alkyl polyglucoside shifts the one phase region to lower temperatures compared with water/toluene/Lutensol ON 50 mixtures. This is contrary to the expectation, considering ...микроемулзија, толуен, алкил полиглукозид, оксоалкохол етоксилат, појачивач ефикасности, „fish“ дијаграми... ON 90, povecava kapacifet rastvaranja površinski aktivne supstance i pomera jednofazni region sistema ka višim temperaturama. Ključne reči: mikroemulzija, toluol, alki! poliglukozid, oksoalkoho! etoksilat, adi- tiv-pojačivač, “iba" dijagram. ...Marija Ilic, Franz-Hubert Haegel, Vesna Pavelkic, Dragan Zlatanovic, Snezana Nikolic-Mandic, Aleksandar Lolic, Zoran Nedic. "The influence of alkyl polyglucosides (and highly ethoxylated alcohol boosters) on the phase behavior of a water/toluene/technical alkyl polyethoxylate microemulsion system" in Chemical Industry and Chemical Engineering Quarterly, National Library of Serbia (2016). https://doi.org/ 10.2298/CICEQ141105015I
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Unusually sluggish microemulsion system with water, toluene and a technical branched alkyl polyethoxylate
Marija Ilić, Franz-Hubert Haegel, Vesna Pavelkić, Snežana Zlatanović, Zoran Marković, Aleksandar Cvjetić (2015)Microemulsion systems with water, toluene and nonionic surfactants are interesting for application due to the excellent solvent properties of aromatic hydrocarbons. In this study, the pseudo-binary phase diagram (“fish-diagram”) of such a ternary system was investigated using a branched technical alkyl polyethoxylate. Lutensol ON 50 (i-C10E5) was considered a suitable surfactant. The system with technical branched i-C10E5 exhibits very long, and for compositions near optimum solubilization, i.e., the minimum content of surfactant needed for a bicontinuous microemulsion, extremely long ...микроемулзија, толуен, оксоалкохол етоксилат, термодинамичка стабилност, тернарни фазни дијаграми, дијаграми „fish“Marija Ilić, Franz-Hubert Haegel, Vesna Pavelkić, Snežana Zlatanović, Zoran Marković, Aleksandar Cvjetić. "Unusually sluggish microemulsion system with water, toluene and a technical branched alkyl polyethoxylate" in Chemical Industry and Chemical Engineering Quarterly (2015). https://doi.org/10.2298/CICEQ141012045I