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84 items
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Crystal structure of K3EuSi2O7
alkalni silikati elemenata retkih zemalja, kristalna struktura, sinteza metodom fluksa, rendgenska difrakcija na monokristalu... and co-authors.13 The crystal structure of the title compound consists of Si2O7 groups and EuO6 polyhedra which form a 3D framework with potassium ions in the holes (Fig. 1). Fig.1. The framework in the crystal structure of K3EuSi2O7 along [001]. Color code: K atoms and polyhedra are black, EuO6 ...
... (2) to 111.0 (4) °. Three potassium cations show three different coordination environments. The coordination sphere of K1 includes eight oxygen ions and forms a K1O2+4+2 coordination polyhedron which can be described as a distorted hexagonal pyra- mid with a split apex [distances range from 2 ...Sabina Kovač, Predrag Dabić, Aleksandar Kremenović. "Crystal structure of K3EuSi2O7" in Journal of the Serbian Chemical Society, National Library of Serbia (2021). https://doi.org/10.2298/JSC210218026K
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Low-temperature phase transition and magnetic properties of K3YbSi2O7
Predrag Dabić, Volker Kahlenberg, Biljana Krüger, Marko Rodić, Sabina Kovač, Jovan Blanuša, Zvonko Jagličić, Ljiljana Karanović, Václav Petříček, Aleksandar Kremenović (2021)alkalni silikati elemenata retkih zemalja, fazni prelazi, magnetne karakteristike, razdvajanje kristalnog polja, silikati lantanica... respectively. Both polymorphs can be described as a three-dimensional framework made up of Si2O7 groups and YbO6 octahedra with large potassium ions located in cavities of the network. The potassium atoms occupy two different crystallographic posi- tions and in both sites they are nine-coordinated ...
... used, respectively. Both polymorphs can be described as a three-dimensional framework made up of SiO, groups and YbO, octahedra with large potassium ions located in cavities of the network. The potassium atoms occupy two different crystallographic posi- tions and in both sites they are nine-coordinated ...
... phase transition is characterized by small shifts of the atomic posi- tions and minor changes in the coordination environments of the potassium ions. The Yb3+ cations are octahedrally coordinated with four oxygen atoms at Yb–O1 distances of 2.212 (4) Å and two oxygen atoms at Yb–O2 distances ...Predrag Dabić, Volker Kahlenberg, Biljana Krüger, Marko Rodić, Sabina Kovač, Jovan Blanuša, Zvonko Jagličić, Ljiljana Karanović, Václav Petříček, Aleksandar Kremenović. "Low-temperature phase transition and magnetic properties of K3YbSi2O7" in Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, International Union of Crystallography (IUCr) (2021). https://doi.org/10.1107/S2052520621006077
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Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering
Josip Išek, Lazar Kaluđerović, Nikola Vuković, Maja Milošević, Ivana Vukašinović, Zorica Tomić (2020)... 1957): Cayo(POa),F> + 9H>SOa + 20H2 O — CaHPO, · 2H,O + 9CaSO, · 2H2,O + 5H,PO, + 2HF (7) During acid digestion of aluminosilicate minerals, AP* ions are first released and then chemically bonded in synthetic Clay Minerals 67 120 In te ns it y Fig. 3. XRD traces of investigated samples. ...
... in chukhrovite, Fe in ferric oxyhydroxide species, etc.), due to their poor solubility, remained in the insoluble residue, while highly soluble ions (Na*, K*, MgŽ*) tended to concentrate in the supernatant. Although the solubility of brushite is a twelfth of that of gypsum, the recrystallization ...Josip Išek, Lazar Kaluđerović, Nikola Vuković, Maja Milošević, Ivana Vukašinović, Zorica Tomić. "Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering" in Clay Minerals, Cambridge University press (2020). https://doi.org/10.1180/clm.2020.11
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An arid phase in the Internal Dinarides during the early to middle Miocene: Inferences from Mg-clays in the Pranjani Basin (Serbia)
N. Andrić-Tomašević, V. Simić, O. Mandic, D. Životić, M. Suárez, E. García-Romero. "An arid phase in the Internal Dinarides during the early to middle Miocene: Inferences from Mg-clays in the Pranjani Basin (Serbia)" in Palaeogeography, Palaeoclimatology, Palaeoecology, Elsevier BV (2020). https://doi.org/10.1016/j.palaeo.2020.110145
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BaTiO3/NixZn1−xFe2O4 (x = 0, 0.5, 1) Composites Synthesized by Thermal Decomposition: Magnetic, Dielectric and Ferroelectric Properties
Marija Šuljagić, Ivan Petronijević, Miljana M. Mirković, Aleksandar Kremenović, Adis Džunuzović, Vladimir B. Pavlović, Aleksandra Kalezić-Glišović, Ljubica Andjelković (2023)To investigate the influence of spinel structure and sintering temperature on the functional properties of BaTiO3/NixZn1−xFe2O4 (x = 0, 0.5, 1), NiFe2O4, ZnFe2O4, and Ni0.5Zn0.5Fe2O4 were in situ prepared by thermal decomposition onto BaTiO3 surface from acetylacetonate precursors. As-prepared powders were additionally sintered at 1150 °C and 1300 °C. X-ray powder diffraction (XRPD) and scanning electron microscopy (SEM) coupled with electron dispersive spectroscopy (EDS) were used for the detailed examination of phase composition and morphology. The magnetic, dielectric, and ...ferroelectric, dielectric properties, magnetic properties, titanate/ferrite composites, phase composition... grains, while also promoting, more pronounced magnetoelectric signals [39]. However, high sintering, temperatures may lead to the formation of FeŽ* ions in such composites, which can cause interphase reactions and decrease electric resistivity, thus lowering the magnetoelectric response [40]. Among ...
... temperature decreases with an increase in Zn content due to the weaken- ing of A-B superexchange interaction caused by the replacement of Fe9+ by Zn?* ions at tetrahedral sites. 20 18|- 16| 144| s | —— ~ Ž 12 - Pl J·\–T··J–r–n–w?–r·)?–«_»–&i%,_ —H;\Jf , 10[ —— BaTiOJNiFe,O, R i s= s . i —c— ...
... anion). The iron(III) acetylacetonate, nickel(II) acetylacetonate, and zinc(II) acetylacetonate were synthesized in a reaction of appropriate metal ions (Fe3+, Ni?*, Zn?**) with ammonium acetylacetonate. The synthesis procedure for obtaining, such ferrite systems Was previ- ously described by Andjelkovic ...Marija Šuljagić, Ivan Petronijević, Miljana M. Mirković, Aleksandar Kremenović, Adis Džunuzović, Vladimir B. Pavlović, Aleksandra Kalezić-Glišović, Ljubica Andjelković. "BaTiO3/NixZn1−xFe2O4 (x = 0, 0.5, 1) Composites Synthesized by Thermal Decomposition: Magnetic, Dielectric and Ferroelectric Properties" in Inorganics, MDPI AG (2023). https://doi.org/10.3390/inorganics11020051
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Оцена перспективности изворишта "Вић баре" за водоснабдевање Обреновца
... which tapping in average 260 I/s of groundwater. The main problems to expanding existing source are the following: higher concentration of Fe and Mn ions in alluvial aquifer waters which stimulate wells’ ageing, reduced summer/autumn Sava riverflows which are the main recharge source, and nevertheless ...Бојан Хајдин, Душан Поломчић, Зоран Стевановић, Драгољуб Бајић, Катарина Хајдин. "Оцена перспективности изворишта "Вић баре" за водоснабдевање Обреновца" in XIV Српски симпозијум о хидрогеологији са међународним учешћем, Рударско-геолошки факултет, Београд (2012)
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Photocatalytic Activity of the V2O5 Catalyst toward Selected Pharmaceuticals and Their Mixture: Influence of the Molecular Structure on the Efficiency of the Process
Sanja J. Armaković, Aleksandra Jovanoski Kostić, Andrijana Bilić, Maria M. Savanović, Nataša Tomić, Aleksandar Kremenović, Maja Šćepanović, Mirjana Grujić-Brojčin, Jovana Ćirković, Stevan Armaković (2023)Due to the inability of conventional wastewater treatment procedures to remove organic pharmaceutical pollutants, active pharmaceutical components remain in wastewater and even reach tap water. In terms of pharmaceutical pollutants, the scientific community focuses on -blockers due to their extensive (over)usage and moderately high solubility. In this study, the photocatalytic activity of V2O5 was investigated through the degradation of nadolol (NAD), pindolol (PIN), metoprolol (MET), and their mixture under ultraviolet (UV) irradiation in water. For the preparation of V2O5, facile ...DFT analysis, metoprolol, nadolol, nanomaterial characterization, photocatalysis, pindolol, β-blocker... hree-times higher degradation rate for PIN (30%). The nature of the substituents attached o the aromatic ring, and the secondary interaction of released ions have significant roles in 0.0 0 ing the investigated compounds” absorption maxima and the UV lamp's characteristics. he degradation progress ...
... compounds that DF decomposes, the pH of the solution plays a vital role in the creation of reactive oxygen species and the further interaction of released ions and radicals. The pH value of the aqueous solutions for DF was about 7.5 + the specified pH value of the aqueous solution, reactive oxygen species ...
... [CrossRef] Srilakshmi, P.; Maheswari, A.; Sajeev, V.; Sivakumar, M. Tuning the optical bandgap of V>Os nanoparticles by doping transition metal ions. Mater. Today Proc. 2019, 18, 1375–1379. [CrossRef] arunakaran, C.; Senthilvelan, S. Vanadia-catalyzed solar photooxidation of aniline. J. Colloid ...Sanja J. Armaković, Aleksandra Jovanoski Kostić, Andrijana Bilić, Maria M. Savanović, Nataša Tomić, Aleksandar Kremenović, Maja Šćepanović, Mirjana Grujić-Brojčin, Jovana Ćirković, Stevan Armaković. "Photocatalytic Activity of the V2O5 Catalyst toward Selected Pharmaceuticals and Their Mixture: Influence of the Molecular Structure on the Efficiency of the Process" in Molecules, MDPI AG (2023). https://doi.org/10.3390/molecules28020655
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Hydrogeochemistry of Uranium in the Groundwaters of Serbia
Marina Ćuk, Maja Todorović, Petar Papić, Jovan Kovačević, Zoran Nikić. "Hydrogeochemistry of Uranium in the Groundwaters of Serbia" in Uranium - Past and Future Challenges, Springer International Publishing Switzerland (2015). https://doi.org/10.1007/978-3-319-11059-2_89
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The influence of alkyl polyglucosides (and highly ethoxylated alcohol boosters) on the phase behavior of a water/toluene/technical alkyl polyethoxylate microemulsion system
Marija Ilic, Franz-Hubert Haegel, Vesna Pavelkic, Dragan Zlatanovic, Snezana Nikolic-Mandic, Aleksandar Lolic, Zoran Nedic (2016)The influence of additives (alkyl polyglucoside, Glucopon 600 CS UP and alcohol ethoxylate C18E100) on the behavior of the water/toluene/Lutensol ON 50 (technical oxoalcohol, i-C10E5) microemulsion system as a function of temperature and composition has been investigated. The phase behavior of the microemulsions was determined by vertical sections through the Gibbs phase prism (fish-like phase diagrams). Alkyl polyglucoside shifts the one phase region to lower temperatures compared with water/toluene/Lutensol ON 50 mixtures. This is contrary to the expectation, considering ...микроемулзија, толуен, алкил полиглукозид, оксоалкохол етоксилат, појачивач ефикасности, „fish“ дијаграми... stability of microemulsions over a large tem- perature range and low surfactant concentration is required for technical applications. Some investigat- ions [1,2] show that the use of surfactants with longer hydrophobic units reduces the amount of surfactant needed for microemulsification due to the ...Marija Ilic, Franz-Hubert Haegel, Vesna Pavelkic, Dragan Zlatanovic, Snezana Nikolic-Mandic, Aleksandar Lolic, Zoran Nedic. "The influence of alkyl polyglucosides (and highly ethoxylated alcohol boosters) on the phase behavior of a water/toluene/technical alkyl polyethoxylate microemulsion system" in Chemical Industry and Chemical Engineering Quarterly, National Library of Serbia (2016). https://doi.org/ 10.2298/CICEQ141105015I
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Inhibitory effect of platinum and ruthenium bipyridyl complexes on porcine pancreatic phospholipase A2
Tina Kamčeva, Jörg Flemmig, Bojana Damnjanović, Jürgen Arnhold, Aleksandar Mijatović, Marijana Petković (2011)Fosfolipaza pankreasa A2 (PLA2) igra važnu ulogu u ćelijskoj homeostazi kao iu procesu karcinogeneze. Efekti metalo-lekova koji se koriste kao hemoterapeutici na aktivnost ovog enzima nisu poznati. U ovom radu, interakcija između PLA2 svinjskog pankreasa i dva odabrana kompleksa prelaznih metala — tetrahloro(bipiridin) platine(IV) ([PtCl4(bipi)]) i dihloro (bipiridin) rutenijum(III)hlorida ([RuCl2(bipi)2) ]Cl)—proučavana je. Laserska desorpcija/jonizacija uz pomoć matriksa, vremenska masa spektrometrija (MALDI-TOF MS) i fluorescentna spektroskopija korišćeni su za analizu aktivnosti enzima u odsustvu i prisustvu metalnih kompleksa i za ...... 760.6 and 782.6 for proton and sodium adducts of PC 16 : 0, 18 : 1, while the shaded groups of peaks with m/z values 569.3 and 498.6 originate from ions of ruthenium and platinum complexes, respectively. The peak group around 569.3 was assigned to [RuCl2(bipy)2]Cl which had lost one chloride anion ...
... 16:0; 760.6 and 782.6 for proton and sodium adducts of PC 16:0, 18:1, while the shaded groups of peaks with m/z values 569.3 and 498.6 originate from ions of ruthenium and platinum complexes, respectively. The peak group around 569.3 was assigned to [RuCl(bipy).]Cl which had lost one chloride anion, followed ...Tina Kamčeva, Jörg Flemmig, Bojana Damnjanović, Jürgen Arnhold, Aleksandar Mijatović, Marijana Petković. "Inhibitory effect of platinum and ruthenium bipyridyl complexes on porcine pancreatic phospholipase A2" in Metallomics, Oxford University Press (OUP) (2011). https://doi.org/10.1039/c1mt00088h
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Structural dissymmetrization of optically anisotropic Grs64±1Adr36±1Sps2 grandite from Meka Presedla (Kopaonik Mt., Serbia)
In this paper, grandite core with Grs64±1Adr36±1Sps2composition was crystallographically studied. This core represents zone A of the macroscopically visiblefive A–E zones of the optically anisotropic Grs58–64 Adr36–42Sps2 grandite. The applied procedure includes the detailed analysis of the powder diffraction patterns, and the Rietveld refinements of the crystal structures in a series of 18 space groups and two mixtures, which were followed by the comparative analysis of the R-values, site occupancy factors, and the bond lengths and angles. Synthesis of all ...Pavle Tančić, Aleksandar Kremenović, Predrag Vulić. "Structural dissymmetrization of optically anisotropic Grs64±1Adr36±1Sps2 grandite from Meka Presedla (Kopaonik Mt., Serbia)" in Powder Diffraction, Cambridge University Press (CUP) (2019). https://doi.org/10.1017/S0885715619000897
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Surface functional groups and degree of carbonization of selected chars from different processes and feedstock
Marija Ilić, Franz-Hubert Haegel, Aleksandar Lolić, Zoran Nedić, Tomislav Tosti, Ivana Sredović Ignjatović, Andreas Linden, Nicolai D. Jablonowski, Heinrich Hartmann (2022)The knowledge ofthe structural and chemical properties of biochars is decisive for their application as technical products. For this reason, methods for the characterization of biochars that are generally applicable and allow quality control are highly desired. Several methods that have shown potential in other studies were used to investigate two activated carbons and seven biochars from different processes and feedstock. The chars were chosen to cover a wide range of chemical composition and structural properties as a hardness ...Biougalj, različiti procesi dobijanja, različite sirovine, površinski aktivne grupe, x-ray, FT-IR,XPS... alkaline ions than wood in the original biomass. There- fore, the ash-content ofthe hydrochars is comparable to that of pyrochars or even higher (Table 4) despite the fact that the ash content increases with increasing carbonization due to the loss of volatile elements. Inorganic ions from hydrochars ...
... 2002; 40: 2801—2815. http://dx.doi.org/10.1016/S0008-6223(02)00196-3. Bucker B, Flores Orozco A, Kemna A. Electrochemical polarization around metallic particles-Part 1: The role of diffuse-layer and volume-diffusion relaxation. Geophysics. 2018; 83: E203-E217. https:// doi.org/10.1190/geo2017-0401 ...
... difference in pH between HW1100g (9.9) and PW700g (7.9) is also in accordance with this finding. The pyrochars made at lower temperature release less ions corre- sponding to low ash content in SW500f as well as in BW550 and the dominant content of SIO> in the ash of HW500f. The leachate of ACI with ...Marija Ilić, Franz-Hubert Haegel, Aleksandar Lolić, Zoran Nedić, Tomislav Tosti, Ivana Sredović Ignjatović, Andreas Linden, Nicolai D. Jablonowski, Heinrich Hartmann. "Surface functional groups and degree of carbonization of selected chars from different processes and feedstock" in PLOS ONE (2022). https://doi.org/10.1371/journal.pone.0277365
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Analysis Of the Process Of Carbon Capture Utilization And Storage In Underground Reservoirs
John Nyame (2024)The importance of mitigating the effects of global climate change has necessitated an in-depth exploration of innovative strategies to reduce carbon dioxide (CO2) emissions. Among these strategies, Carbon Capture, Utilization, and Storage (CCUS) has emerged as a promising and transformative solution. This master thesis delves into the diverse realm of CCUS processes, aiming to unravel the positives challenges, and opportunities within this dynamic field. The analysis begins with a systematic examination of carbon capture technologies, encompassing post-combustion, pre-combustion, and oxy-fuel combustion ...... desalination process flow diagram. First, the Mg?* and Ca** ions from desalination wastewater are separated via the pH swing method; thereafter, sodium hydroxide (NaOH) obtained via desalination wastewater electrolysis is used. The Mg** and Ca** ions are sequentially converted to magnesium hydroxide (Me(OH)>) ...
... the cost of the process [15]. If brine, mixed with ammonia is exposed to CO2, already-weak bonds start to form, which leads to the removal of the ions from the water phase. The products sodium bicarbonate and ammonium chloride are heavy and, thus, can easily settle to the bottom of the tank. The ...John Nyame. Analysis Of the Process Of Carbon Capture Utilization And Storage In Underground Reservoirs, 2024
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The Importance of Detailed Groundwater Monitoring for Underground Structure in Karst (Case Study: HPP Pirot, Southeastern Serbia)
... concentrations near PP-3 increased and altered the natural qualitative and quantitative parameters of the groundwater. High concentrations of these ions were also detected in water samples from tunnel sections 1 + 815 m and 1 + 970 m, which correspond to the location of observation well PP-1. This indicated ...Marina Čokorilo Ilić, Ana Mladenović, Marina Ćuk, Igor Jemcov. "The Importance of Detailed Groundwater Monitoring for Underground Structure in Karst (Case Study: HPP Pirot, Southeastern Serbia)" in Water, MDPI AG (2019). https://doi.org/10.3390/w11030603
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NMR kinetic studies of the interactions between [Ru(terpy)(bipy)(H2O)]2+ and some sulfur-donor ligands
Aleksandar Mijatović, Biljana Šmit, Ana Rilak, Biljana Petrović, Dragan Čanović, Živadin D. Bugarčić (2012)Reakcije supstitucije monofunkcionalnog [Ru(terpi)(bipi)(H2O)]2+ kompleksa, gde je terpi = 2,2′:6′,2″-terpiridin i bipi = 2,2′-bipiridin, sa biološki relevantnim sumporo donorskim ligandima, kao što su tiourea, l-metionin, l-cistein i glutation, proučavane su u vodenim rastvorima tehnikom 1H i 13C NMR spektroskopije. Sve reakcije su proučavajne na pH 7,4, u prisustvu fosfatnog pufera, da bi se oponašalo fiziološko okruženje tokom procesa supstitucije. Reakcije se izvode na 295 K pod uslovima reakcija drugog reda. Uočeni rezultati pokazuju da brzina supstitucije snažno zavisi ...Aleksandar Mijatović, Biljana Šmit, Ana Rilak, Biljana Petrović, Dragan Čanović, Živadin D. Bugarčić. "NMR kinetic studies of the interactions between [Ru(terpy)(bipy)(H2O)]2+ and some sulfur-donor ligands" in Inorganica Chimica Acta, Elsevier BV (2012). https://doi.org/10.1016/j.ica.2012.09.016
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Geochemical study of U, Th and REE mineralizations in Jurassic sediments and hydrochemical characterization of groundwaters in Eastern Serbia – Case study: Plavna area
Jovan Kovačević, Maja Todorović, Marina Ćuk, Petar Papić . "Geochemical study of U, Th and REE mineralizations in Jurassic sediments and hydrochemical characterization of groundwaters in Eastern Serbia – Case study: Plavna area" in Carpathian Journal of Earth and Environmental Sciences (2016)
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Crystallography and Surface Oxidation of Stoichiometric Arsenopyrite from Šumadija-Kopaonik Pb-Zn/Polymetallic Ore District (Serbia)
Ivana Jelić, Aleksandar Pačevski, Aleksandar Kremenović, Aleš Šoster, Andreja Šestan, Janez Zavašnik (2023)The behaviour and stability of arsenopyrite largely depend on its crystal structure, but studies of crystallography and structural defects are scarce. For clarification, we investigated a series of natural arsenopyrite crystals from the polymetallic Pb-Zn-(±Cu,Ag,Au,Sb,Bi,W) Šumadija-Kopaonik ore district (Serbia) by powder X-ray diffraction (XRPD). Among them, samples from the Drenjak gold mineralisation showed near-stoichiometric FeAsS composition and were further investigated by conventional and high-resolution transmission electron microscopy methods. TEM revealed abundant planar crystallographic defects and epitaxial surface oxide layer ...Inorganic Chemistry, Condensed Matter Physics,General Materials Science, General Chemical Engineering, crystal structure, FeAsS, oxidation, TEM, XRPD... (FeAsS) is worldwide abundant natural sulphide, common in various mineral deposit types [1]. Arsenopyrite can incorporate significant amounts of metal ions, such as gold, cobalt, and nickel, either accommodated in the crystal structure in a solid so- lution or as micro-inclusions [2,3]. In particular ...Ivana Jelić, Aleksandar Pačevski, Aleksandar Kremenović, Aleš Šoster, Andreja Šestan, Janez Zavašnik. "Crystallography and Surface Oxidation of Stoichiometric Arsenopyrite from Šumadija-Kopaonik Pb-Zn/Polymetallic Ore District (Serbia)" in Crystals, MDPI AG (2023). https://doi.org/10.3390/cryst13020278
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Laboratory Testing of Nanosilica- Reinforced Silicate and Polyacrylamide Gels
Irina Zahirovic, Dušan Danilović, Milica Šuput Vranjin, Miloš Tripković. "Laboratory Testing of Nanosilica- Reinforced Silicate and Polyacrylamide Gels" in SPE Journal (2023)
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Trace elements and garnet formation in a distal skarn zone: a case study of the Rudnik deposit, Central Serbia
Bojan Kostić, Pavle Tančić, Natalija Batoćanin. "Trace elements and garnet formation in a distal skarn zone: a case study of the Rudnik deposit, Central Serbia" in Geological Quarterly, septembar 2024, Polish Geological Institute - National Research Institute (PGI-NRI) (2024). https://doi.org/10.7306/gq.1752
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A Model for Determining Fuzzy Evaluations of Partial Indicators of Availability for High-Capacity Continuous Systems at Coal Open Pits Using a Neuro-Fuzzy Inference System
This paper presents a model for determining fuzzy evaluations of partial indicators of the availability of continuous systems at coal open pits using a neuro-fuzzy inference system. The system itself is a combination of fuzzy logic and artificial neural networks. The system availability is divided into partial indicators. By combining the fuzzy logic and artificial neural networks, a model is obtained that has the ability to learn and uses expert judgment for that learning. This paper deals with the ...системи, континуални системи експлоатације (роторни багер-транспортер-дробилично постројење), рударство, расположивост, меко рачунарство, фази логика, ANN, ANFISMiljan Gomilanović, Miloš Tanasijević, Saša Stepanović, Filip Miletić. "A Model for Determining Fuzzy Evaluations of Partial Indicators of Availability for High-Capacity Continuous Systems at Coal Open Pits Using a Neuro-Fuzzy Inference System" in Energies, MDPI AG (2023). https://doi.org/10.3390/en16072958