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150 items
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Interactions of Copper(II) Complexes of some Schiff base ligands with calf thymus DNA and bovine serum albumin
Joni prelaznih metala u kombinaciji sa različitim ligandima nude veliki broj mogućnosti za ispitivanje potencijalnih bioaktivnosti. Među jonima prelaznih metala, bakar je poznat kao endogeni metal za ljude, sa karakterističnim biološkim redoks aktivnostima i relativno jakim afinitetom za nukleobaze. Kompleksi bakra ispoljavaju svoju antitumornu aktivnost na nekoliko različitih načina, generišu veliku količinu ROS, što uzrokuje oksidativno oštećenje mitohondrija i biomakromolekula. Nađeno je da kompleksi bakra(II) imaju umeren do dobar afinitet vezivanja sa DNK, uglavnom putem interkalacije.Angelina Petrović, Aleksandar Mijatović, Rada Baošić, Jovana Bogojeski. "Interactions of Copper(II) Complexes of some Schiff base ligands with calf thymus DNA and bovine serum albumin" in 6. Konferencija mladih hemičara Srbije, Srpsko hemijsko društvo (2018)
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Енергетска транзиција система даљинског грејања - могућности и изазови
Марија Живковић, Дејан Ивезић (2023)Највише енергије у зградама у Србији троши се на загревање простора. Због тога ће системи даљинског грејања имати важну улогу у процесу транзиције целокупног енергетског сектора. Мере и активности морају да буду усмерене и на потрошњу и производњу енергије. У раду је дат преглед потенцијала различитих обновљивих и алтернативних извора енергије, који се могу користити за производњу топлотне енергије. Приказани резултати су приказани са различитим нивоом детаљности, у зависности од расположивих података, а који могу да служе као ...Марија Живковић, Дејан Ивезић . "Енергетска транзиција система даљинског грејања - могућности и изазови" in Стручно-научна конференција ТОПС 2023, Златибор, Србија, мај 2023., Шабац : Пословно удружење "Топлане Србије" (2023)
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Место и улога система даљинског грејања у стратешким плановима развоја енергетског сектора Републике Србије
Dejan Ivezić, Marija Živković (2022)Системи даљинског грејања представљају врло битан елемент енергетског система Републике Србије. Инжењерски посматрано, ради се о системима који су концептуално осмишљени у другој половини ХХ века и чије функционисање почива на коришћењу фосилних горива. Трансформација ових система, у склопу енергетске транзиције читавог енергетског система Републике Србије, претпоставља, између осталог, значајније коришћење обновљивих извора енергије у производњи топлотне енергије, смањење губитака и повећање енергетске ефикасности производње и дистрибуције енергије, дигитализацију процеса, итд. У раду се укратко излаже тренутно стање система ...Dejan Ivezić, Marija Živković. "Место и улога система даљинског грејања у стратешким плановима развоја енергетског сектора Републике Србије" in Стручно-научна конференција ТОПС 2022, Златибор 30-31.05.2022., Зборник радова, Пословно удружење Топлане Србије (2022)
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Osnaživanje energetske tranzicije u sektoru domaćinstva u Srbiji: integrativni pristup
Boban Pavlović (2023)Glavni cilj istraživanja bio je da se razvije metodološki pristup koji bi podržao proces energetskog planiranja tranzicije u grejanju domaćinstava, uzimajući u obzir specifičnosti ovog sektora. Kako bi se procenili mogući tokovi energetske tranzicije u grejanju domaćinstava i analizirali politički instrumenti za ubrzanje ovog procesa, razvijen je simulacioni model zasnovan na agentima (Agent Based Model – ABM). Simulacioni model je primenjen na slučaju energetske tranzicije u sektoru domaćinstva u Srbiji. Prethodno su kroz istraživanje prikupljeni podaci o grejanju domaćinstava ...energetska tranzicija, energetsko planiranje, energetsko modeliranje, obnovljivi izvori energije, domaćinstva, ponašanje potrošačaBoban Pavlović. "Osnaživanje energetske tranzicije u sektoru domaćinstva u Srbiji: integrativni pristup" in Energija, ekonomija, ekologija (2023)
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Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands
A series of novel ternary Co(II), Ni(II) and Cu(II) complexes containing 2,20-dipyridylamine (dipya), 2,20-bipyridine (bipy), and 1,10-phenanthroline (phen), as aromatic diamine ligands, and dianion of isophthalic acid (ipht) have been prepared by ligand exchange reactions from diluted H2O/EtOH solutions. The complexes were characterized by elemental analysis, IR spectroscopy, magnetic susceptibility measurements and TG and DSC analysis. Three complexes, Cu(dipya)(ipht)H2O (1), Co(dipya)(ipht)2H2O (2) and Cu(ipht)(phen)2H2O (5) are polymeric with bis-monodentate ipht, while the other two complexes M(bipy)(ipht)4H2O, M@Co(II) (3) and ...комплекси прелазних метала, карбоксилатни лиганди, N-лиганди, кристална структура, магнетна својстваJelena Rogan, Dejan Poleti, Ljiljana Karanović, Zvonko Jagličić. "Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands" in Journal of Molecular Structure, Elsevier BV (2011). https://doi.org/10.1016/j.molstruc.2010.11.024
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Water in the Alluaudite Type-Compounds: Synthesis, Crystal Structure and Magnetic Properties of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H,□)0.5(H2O,H3O)0.5]2x+
In this study, a new cobalt arsenate belonging to the alluaudite supergroup compounds with the general formula of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H, )0.5(H2O,H3O)0.5]2x+ (denoted as CoAsAllu) was synthesized under hydrothermal conditions. Its crystal structure was determined by a room-temperature single-crystal X-ray diffraction analysis: space group C2/c, a = 11.6978(8), b = 12.5713(7), c = 6.7705(5) Å, b = 113.255(5)◦, V = 914.76(11) Å3, Z = 2 for As6H8Co6O25. It represents a new member of alluaudite-like protonated arsenates and the first alluaudite-like phase ...супергрупа алуаудита, арсенати прелазних метала, хидротермална синтеза, кристална структура, хидратисани хидрокси-арсенати, стехиометрија, магнетна својстваTamara Đorđević, Ljiljana Karanović, Marko Jagodič, Zvonko Jagličić. "Water in the Alluaudite Type-Compounds: Synthesis, Crystal Structure and Magnetic Properties of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H,□)0.5(H2O,H3O)0.5]2x+" in Minerals, MDPI AG (2021). https://doi.org/10.3390/min11121372
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Inhibitory effect of platinum and ruthenium bipyridyl complexes on porcine pancreatic phospholipase A2
Tina Kamčeva, Jörg Flemmig, Bojana Damnjanović, Jürgen Arnhold, Aleksandar Mijatović, Marijana Petković (2011)Fosfolipaza pankreasa A2 (PLA2) igra važnu ulogu u ćelijskoj homeostazi kao iu procesu karcinogeneze. Efekti metalo-lekova koji se koriste kao hemoterapeutici na aktivnost ovog enzima nisu poznati. U ovom radu, interakcija između PLA2 svinjskog pankreasa i dva odabrana kompleksa prelaznih metala — tetrahloro(bipiridin) platine(IV) ([PtCl4(bipi)]) i dihloro (bipiridin) rutenijum(III)hlorida ([RuCl2(bipi)2) ]Cl)—proučavana je. Laserska desorpcija/jonizacija uz pomoć matriksa, vremenska masa spektrometrija (MALDI-TOF MS) i fluorescentna spektroskopija korišćeni su za analizu aktivnosti enzima u odsustvu i prisustvu metalnih kompleksa i za ...... addition of these transition metal complexes to the large unilamellar vesicles formed from PC, which contained carboxyfluorescein, increased significantly the leakage of this dye. This effect might be caused by changes in the phospholipid organization after addition of transition metal complexes. ...
... so far and the effect of transition metal complexes on the activity of this enzyme has not been studied. In this work, this enzyme serves only as a model system for the study of the effect of these chemotherapeutic drugs on the PLA2 activity. One can assume that transition metal complexes will exhibit ...
... that inhibitors of sPLA2, such as transition metal complexes, might contribute to the processes of inhibition of prostate tumor growth and differentiation, i.e. that they will have rather beneficial effects. In addition, inhibition of secre- tory PLA2 with transition metal complexes might affect the ...Tina Kamčeva, Jörg Flemmig, Bojana Damnjanović, Jürgen Arnhold, Aleksandar Mijatović, Marijana Petković. "Inhibitory effect of platinum and ruthenium bipyridyl complexes on porcine pancreatic phospholipase A2" in Metallomics, Oxford University Press (OUP) (2011). https://doi.org/10.1039/c1mt00088h
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Effect of Properties of Working Fluids on the Efficiency of a Low-Temperature Organic Rankine Cycle
Decarbonization of all segments of energy systems, both on the supply and demand side, is one of the main goals of the energy transition. Electricity supply in the future will largely rely on generation from intermittent energy sources: wind and solar. Locally available, non-utilized alternative low-temperature energy sources as hydro-geothermal wells, and abounded oil and gas wells, have the potential to provide continual energy production over the year. Electricity generation from these energy sources is carried out with working ...Marija Živković, Aleksandar Mijatović, Dejan Ivezić, Boban Pavlović. "Effect of Properties of Working Fluids on the Efficiency of a Low-Temperature Organic Rankine Cycle" in The 21st International Conference on Thermal Science and Engineering of Serbia, Niš, Serbia, October 2024, University of Niš, Faculty of Mechanical Engineering in Niš (2024)
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Determination of Mechanical Properties of Altered Dacite by Laboratory Methods
This paper presents a methodology for determining the uniaxial and triaxial compressive strength of heterogeneous material composed of dacite (D) and altered dacite (AD). A zone of gradual transition from altered dacite to dacite was observed in the rock mass. The mechanical properties of the rock material in that zone were determined by laboratory tests of composite samples that consisted of rock material discs. However, the functional dependence on the strength parameter alteration of the rock material (UCS, intact ...... determining the uniaxial and triaxial compressive strength of heterogeneous material composed of dacite (D) and altered dacite (AD). A zone of gradual transition from altered dacite to dacite was observed in the rock mass. The mechanical properties of the rock material in that zone were determined by laboratory ...
... as a basis for assessing rock mass parameters. Therefore, it is possible to predict the strength parameters of the heterogeneous rock mass at the transition of hard (D) and weak rock (AD) based on all calculated strength parameters for different participation of AD. Keywords: dacite; altered dacite; ...
... determining the uniaxial and triaxial compressive strength of heterogeneous material composed of dacite (D) and altered dacite (AD). A zone of gradual transition from altered dacite to dacite was observed in the rock mass. The mechanical properties of the rock material in that zone were determined by laboratory ...Veljko Rupar, Vladimir Čebašek, Vladimir Milisavljević, Dejan Stevanović, Nikola Živanović. "Determination of Mechanical Properties of Altered Dacite by Laboratory Methods" in Minerals, MDPI AG (2021). https://doi.org/10.3390/min11080813
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Microemulsion with aromatic oil as cleaner media for electropolymerisation
Abstract Microemulsion polymerization is widely used as a cleaner alternative way to prepare intrinsically conductive polymers. We studied isothermal phase diagrams for microemulsions of the electropolymerizable heterocyclic aromatic oil 3,4-ethylenedioxythiophene (EDOT), aqueous LiClO4 solution and alkyl polyethoxylate. Our specific goal was to assess the effect of LiClO4 salt on the phase behaviour. The phase behaviour was characterized by stepwise titration and microscopic analyses. Here we found that the increase of the concentration of LiClO4 salt shifts the microemulsion region ...M. Ilić, F.-H. Haegel, S. Zlatanovic, N. Potkonjak, B. Simonovic. "Microemulsion with aromatic oil as cleaner media for electropolymerisation" in Environmental Chemistry Letters, Springer Science and Business Media LLC (2005). https://doi.org/10.1007/s10311-005-0101-3
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Manganese-pyromellitate complex as a precursor for preparation of spinel Mn3O4
Lidija Radovanović, Željko Radovanović, Aleksandar Kremenović, Bojana Simović, Milica V. Vasić, Jelena Rogan (2022)In recent years, thermal decomposition studies of transition metal complexes with benzenepolycarboxylate ligands have become an area of a great importance due to the possibility of obtaining useful metal oxides with desirable electrical, magnetic and catalytic properties [1]. As a contrast to conventional methods for the preparation of metal oxides, such as hydrothermal or sol–gel treatment, thermolysis is faster, more efficient ...Lidija Radovanović, Željko Radovanović, Aleksandar Kremenović, Bojana Simović, Milica V. Vasić, Jelena Rogan. "Manganese-pyromellitate complex as a precursor for preparation of spinel Mn3O4 " in XIV Conference of chemists, technologists and environmentalists of Republic of Srpska, Academy of sciences and arts of the Republic of Srpska, Banja Luka, Republic of Srpska, B&H, October 21st-22nd, 2022, University in Banjaluka, Faculty of Technology (2022)
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Influence of Ag doping on the morphological and magnetic properties in CuO nanopowders
Maria Čebela, Uroš Čakar, Vesna Lojpur, Maja Milošević, Sanja Krstić, Vladimir Dodevski, Milena Rosić (2023)... as 230 K [1]. Multiferroic phase is present above the first order phase transition at 7x; = 213 K and exists up to the subsequent first order phase transition 7 = 230 K [1,.2]. It was shown that disorder in the form of impurities can stabilize the ferroelectric phase [2] this was our motivation ...Maria Čebela, Uroš Čakar, Vesna Lojpur, Maja Milošević, Sanja Krstić, Vladimir Dodevski, Milena Rosić. "Influence of Ag doping on the morphological and magnetic properties in CuO nanopowders" in Programme ; and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia , Beograd : Institut za multidisciplinarna istraživanja, (2023)
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Analogue modelling of strain partitioning along a curved strike-slip fault system during backarc-convex orocline formation: Implications for the Cerna-Timok fault system of the Carpatho-Balkanides
Nemanja Krstekanić, Ernst Willingshofer, Taco Broerse, Liviu Matenco, Marinko Toljić, Uroš Stojadinović (2021)... northward translation is followed by a phase of combined translation and rotation. The purpose of these two phases of imposed kinematics is to create strike-slip deformation (in the first phase) and to study influ- ence of coupled rotation and translation (the second-phase) on the pre-existing strike-slip ...
... (Lmodel/Lnature) of 1.43∙10−6. We choose the length scale ratio such that the brittle-viscous transition in the models is at a depth of ca. 10 km when scaled to nature. This depth of the brittle-viscous transition is consistent with a change in deformation behavior of quartz-dominated lithologies from ...
... implications for the style and kinematics of deformation at the transition of the strike-slip to the thrusting domain where M1 shows a gradual change from thrusting to strike-slip deformation (Fig. 3e and f). In contrast, this transition is abrupt in M7 and defined by an array of small dextral faults ...Nemanja Krstekanić, Ernst Willingshofer, Taco Broerse, Liviu Matenco, Marinko Toljić, Uroš Stojadinović. "Analogue modelling of strain partitioning along a curved strike-slip fault system during backarc-convex orocline formation: Implications for the Cerna-Timok fault system of the Carpatho-Balkanides" in Journal of Structural Geology, Elsevier BV (2021). https://doi.org/10.1016/j.jsg.2021.104386
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Possibilities for Reduction of Energy-Related Air Pollution in Serbia - Exploring Energy Scenarios
Fossil fuels and biomass account for almost 93% of the total primary energy supply in Serbia. Meeting the energy needs of consumers implies a transformation of the chemical energy of fuels through combustion processes to obtain heat that can be utilized as such, or further transformed into mechanical or electrical energy. These processes have an undeniable impact on air pollution, even in cases of biofuels or hydrogen combustion. Possibilities for air pollution reduction are identified, both on the supply ...Marija Živković, Boban Pavlović, Dejan Ivezić, Aleksandar Mijatović. "Possibilities for Reduction of Energy-Related Air Pollution in Serbia - Exploring Energy Scenarios" in 9th International Conference Mining and Environmental Protection, 24.-27. May 2023, Sokobanja, Serbia, Belgrade, Serbia : University of Belgrade, Faculty of Mining and Geology (2023)
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Fluid inclusion study in quartz of the Rudnik Pb-Zn-Cu-Ag skarn deposit, Serbia
Six types of fluid inclusions were identified in three growth zones of hydrothermal quartz from the Rudnik skarn deposit. In the core zone, primary two-phase fluid inclusions of high (type 1) and moderate salinity (type 2) homogenized to liquid between 350-430 °C and 340-420 °C, respectively. Raman analysis revealed that the vapour phases are a CO2-CH4 gas mixture, with a predominance of CO2. The core contains and dispersed vapour-rich fluid inclusions of low salinity (type 3) composed of CO2-CH4-H2S ...Stefan Petrović, Ronald J. Bakker, Vladica Cvetković, Rade Jelenković. "Fluid inclusion study in quartz of the Rudnik Pb-Zn-Cu-Ag skarn deposit, Serbia" in Mineral Resources in a Changing World-17th SGA Biennial Meeting, Zurich, between 28th August and 1st September 2023, Genéve : Society for Geology Applied to Mineral Deposits (2023)
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A tool for identifying the criticality in the disordered systems with metastable dynamics
Svetislav Mijatović, Dragutin Jovković, Sanja Janićević, Stefan Graovac, Đorđe Spasojević. "A tool for identifying the criticality in the disordered systems with metastable dynamics" in Physica A: Statistical Mechanics and its Applications, Elsevier BV (2021). https://doi.org/10.1016/j.physa.2021.125883
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Structure, interaction with biomolecules, and cytotoxicity of copper (II) complexes chelating some Schiff base ligands
Aleksandar Mijatović, Angelina Z. Caković, Aleksandar Lolić, Olivera Klisurić, Marko N. Živanović, Dragana S. Šeklić, Snežana Sretenović, Marija Ilić, Jovana Bogojeski (2023)Cancer remains one of the world's deadliest diseases, claiming many lives each day. Transition metal complexes are leading candidates in developing anticancer agens with cisplatin used in chemotherapy worldwide. Copper, an endogenous metal in the human body, is especially attractive because of its typical redox biological activities and a relatively strong affinity to nucleobases. A series of Cu(II) complexes with ethane-1,2-diamine as the amine part and pentane-2,4-dione and/or 1-phenylbutane-1,3-dione, pentane-2,4-dione and/or 1,1,1- trifluoropentane-2,4-dione, or 1,1,1-trifluoropentane-2,4-dione and/or 1-phenylbutane-1,3-dione as the ...Aleksandar Mijatović, Angelina Z. Caković, Aleksandar Lolić, Olivera Klisurić, Marko N. Živanović, Dragana S. Šeklić, Snežana Sretenović, Marija Ilić, Jovana Bogojeski. "Structure, interaction with biomolecules, and cytotoxicity of copper (II) complexes chelating some Schiff base ligands" in Applied Organometallic Chemistry, Wiley (2023). https://doi.org/10.1002/aoc.7253
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New paleoecological perspectives on Late Pleistocene Neanderthals in northern Balkans: the rodent assemblages from Smolućka cave (Serbia)
Mihailo Jovanović, Katarina Bogićević, Draženko Nenadić, Jordi Agustí,·Christian Sánchez Bandera, Juan Manuel López García, Hugues Alexandre Blain (2022)During the Late Pleistocene, the Balkans came to be an important region with many isolated areas, enabling fauna, alongside Neanderthals, to thrive in the area. This work is focused on paleoenvironmental and paleoclimatic changes that occurred in the northern Balkan Peninsula with a special focus on fossil record from Smolućka cave aging from MIS 5 to MIS 3. Based on available data, an attempt has been made to establish a synthetic chronological context for the faunal assemblages recovered from ...Mihailo Jovanović, Katarina Bogićević, Draženko Nenadić, Jordi Agustí,·Christian Sánchez Bandera, Juan Manuel López García, Hugues Alexandre Blain. "New paleoecological perspectives on Late Pleistocene Neanderthals in northern Balkans: the rodent assemblages from Smolućka cave (Serbia)" in Archaeological and Anthropological Sciences (2022)
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Photocatalytic Activity of the V2O5 Catalyst toward Selected Pharmaceuticals and Their Mixture: Influence of the Molecular Structure on the Efficiency of the Process
Sanja J. Armaković, Aleksandra Jovanoski Kostić, Andrijana Bilić, Maria M. Savanović, Nataša Tomić, Aleksandar Kremenović, Maja Šćepanović, Mirjana Grujić-Brojčin, Jovana Ćirković, Stevan Armaković (2023)Due to the inability of conventional wastewater treatment procedures to remove organic pharmaceutical pollutants, active pharmaceutical components remain in wastewater and even reach tap water. In terms of pharmaceutical pollutants, the scientific community focuses on -blockers due to their extensive (over)usage and moderately high solubility. In this study, the photocatalytic activity of V2O5 was investigated through the degradation of nadolol (NAD), pindolol (PIN), metoprolol (MET), and their mixture under ultraviolet (UV) irradiation in water. For the preparation of V2O5, facile ...DFT analysis, metoprolol, nadolol, nanomaterial characterization, photocatalysis, pindolol, β-blocker... v—photon"s frequency, E, g—bandgap, A—proportional con- stant, and the n factor depends on the nature of the electron transition. They equal 1/2 or 2 for allowed direct and indirect transition band gaps [36]. The band gap values were deduced by extrapolating the linear portion of the curves to the energy ...
... is not often easy to decide which type of electron inter-band transition is predominant [37]. According to a detailed analysis of available literature data and the film properties, Schneider concluded that the direct allowed transition could be considered the most probable in investigated V>»Os ...
... nanoparticles based on the best line fitting of Kubelka-Munk functions. Still, in our case, it is impossible to decide the character of the allowed transition, considering the good quality of line fitting (Figure 6). In this work, the DFT approach was used to perform band structure calculations to ...Sanja J. Armaković, Aleksandra Jovanoski Kostić, Andrijana Bilić, Maria M. Savanović, Nataša Tomić, Aleksandar Kremenović, Maja Šćepanović, Mirjana Grujić-Brojčin, Jovana Ćirković, Stevan Armaković. "Photocatalytic Activity of the V2O5 Catalyst toward Selected Pharmaceuticals and Their Mixture: Influence of the Molecular Structure on the Efficiency of the Process" in Molecules, MDPI AG (2023). https://doi.org/10.3390/molecules28020655
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Natural two-dimensional pyrophyllite: Nanoscale lubricant, electrical insulator and easily-machinable material
Borislav Vasić, Radoš Gajić, Ivana Milošević, Žarko Medić, Marina Blagojev, Marko Opačić, Aleksandar Kremenović, Dejan Lazić (2022)Pyrophyllite, with the chemical formula Al2Si4O10(OH)2, is a naturally occurring and abundant van der Waals mineral belonging to the group of phyllosilicates. It is very soft, layered crystal used for sculpting and an excellent electrical and thermal insulator aimed for the operation at high pressure and temperature. Here, for the first time, two-dimensional (2D) pyrophyllite obtained by both mechanical and liquid phase exfoliation is presented and investigated at the nanoscale. The layered structure provides low friction coefficient of around ...Atomic force microscopy, Insulating properties, Nanofriction and wear, Natural two dimensional materials, Phyllosilicates, PyrophylliteBorislav Vasić, Radoš Gajić, Ivana Milošević, Žarko Medić, Marina Blagojev, Marko Opačić, Aleksandar Kremenović, Dejan Lazić. "Natural two-dimensional pyrophyllite: Nanoscale lubricant, electrical insulator and easily-machinable material" in Applied Surface Science, Elsevier BV (2022). https://doi.org/10.1016/j.apsusc.2022.155114