Претрага
264 items
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Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes
Reakcije supstitucije monofunkcionalnih kompleksa [(TLtBu)PdCl]+ i [Pd(tpdm)Cl]+, gde je TLtBu = 2,6-bis[(1,3-di-terc-butilimidazolin-2-imino)metil]piridin i tpdm = terpiridindimetan, sa nukleofilima kao što su: tiourea, I−, Br−, NO2−, piridin i dimetil-sulfoksid (DMSO) proučavani su u 0,1 M vodenom rastvoru NaClO4 u prisustvu 10 mM NaCl. Reakcije su sprovedene na tri različite temperature (288, 298 i 308 K) korišćenjem tehnike zaustavljenog protoka na različitim temperaturama. Reakcije supstitucije su praćene pod uslovima pseudo prvog reda sa velikim viškom nukleofila. Dobijeni rezultati pokazuju da kompleks ...Aleksandar Mijatović, Jovana Bogojeski, Biljana Petrović, Živadin D. Bugarčić. "Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes" in Inorganica Chimica Acta, Elsevier BV (2011). https://doi.org/10.1016/j.ica.2011.11.031 М22
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Environmental flows and demands for sustainable water use in protected karst areas of the Western Balkans
Karst terrains cover some 30% of the Western Balkans, where rich karst aquifers represent the main source of potable water supply and ensure the development of local economies and tourism. In this “classical karst” region, there are also numerous sites or areas under different forms of protection—from those that are included in the UNESCO World Heritage list to natural monuments and landscapes that are protected by national legislation. In and around them are specific representatives of flora and fauna ...Zoran Stevanović, Aleksandra Maran Stevanović, Želimir Pekaš, Romeo Eftimi, Veljko Marinović. "Environmental flows and demands for sustainable water use in protected karst areas of the Western Balkans" in Carbonates and Evaporites, Springer Science and Business Media LLC (2021). https://doi.org/10.1007/s13146-021-00754-1 М22
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An update on the mineral-like Sr-containing transition metal arsenates
Tamara Đorđević, Ljiljana Karanović (2021)We report on the crystal structures of three novel synthetic SrM-arsenates (M = Ni and Fe3+), isostructural or structurally related to the minerals from tsumcorite, carminite and brackebuschite groups. They were synthesised under mild hydrothermal conditions and further characterised using single-crystal X-ray diffraction (SXRD), scanning electron microscopy with energy dispersive spectroscopy (SEMEDS) and Raman spectroscopy. SXRD and SEM-EDS yielded formulae: (I) SrNi2(AsO4)2·2H2O, (II) Sr1.4Fe3+ 1.6(AsO4)2(OH)1.6 and (III) SrFe3+(AsO4)(AsO3OH). All three structures are built up of slightly distorted MO6 octahedra ...арсенати метала, кристална структура, дифракција рендгенских зрака на монокристалима, хидротермална синтеза, Раманова спектроскопија, релевантна једињења у животној средини, арсенeochemistry and PetrologyTamara Đorđević, Ljiljana Karanović. "An update on the mineral-like Sr-containing transition metal arsenates" in Mineralogical Magazine, Mineralogical Society (2021). https://doi.org/10.1180/mgm.2021.41 М22
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Environmental flows and demands for sustainable water use in protected karst areas of the Western Balkans
Karst terrains cover some 30% of the Western Balkans, where rich karst aquifers represent the main source of potable water supply and ensure the development of local economies and tourism. In this “classical karst” region, there are also numerous sites or areas under different forms of protection—from those that are included in the UNESCO World Heritage list to natural monuments and landscapes that are protected by national legislation. In and around them are specific representatives of flora and fauna ...Zoran Stevanović, Aleksandra Maran Stevanović, Želimir Pekaš, Romeo Eftimi, Veljko Marinović. "Environmental flows and demands for sustainable water use in protected karst areas of the Western Balkans" in Carbonates and Evaporites, Springer Science and Business Media LLC (2022). https://doi.org/10.1007/s13146-021-00754-1 М22
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Design of the Opencast Coal Mine Drmno Dewatering System
Development of mining in the opencast mine Drmno from Kostolac basin in Serbia is carried out in the increasingly complex geological and hydro geological conditions with the decline of the coal seams to the alluvial part of Europe's largest river Danube. Greater depth and inflow of groundwater significantly increase costs for dewatering facilities construction with the requirement for optimizing of this more and more important surface mining process. Making decision on screen construction in the opencast mine with redesign ...dewatering system, groundwater, hydrodynamic model, dewatering wells, screen, reliability, environmental effects.Vladimir Pavlović, Dušan Polomčić, Tomislav Šubaranović. "Design of the Opencast Coal Mine Drmno Dewatering System" in Proceedings of the 12th International Symposium Continuous Surface Mining - Aachen 2014, Springer International Publishing (2014). https://doi.org/10.1007/978-3-319-12301-1_11 М33
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Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes
Goran Marković, Aleksandar Ž. Kostić, Nebojša Đ. Pantelić, Radojka Maletić, Jana Štrbački, Jovan Cakić, Lazar Kaluđerović, Biljana P. Dojčinović, Angelo Maria Giuffrè, Jelena B. Popović-Djordjević (2023)Lakes and reservoirs are the main water resources for household, irrigation, and industrial use. Hence, it is necessary to control water pollution and have reliable information on water quality, which refers to its suitability for a particular purpose. The main objective of this study was to evaluate the suitability of water for drinking and irrigation purposes from ten artificial lakes on the territory of the Republic of Serbia. The physicochemical parameters were determined using standard analytical methods, whereas the ...Goran Marković, Aleksandar Ž. Kostić, Nebojša Đ. Pantelić, Radojka Maletić, Jana Štrbački, Jovan Cakić, Lazar Kaluđerović, Biljana P. Dojčinović, Angelo Maria Giuffrè, Jelena B. Popović-Djordjević. "Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes" in Environmental Monitoring and Assessment, Springer Science and Business Media LLC (2023). https://doi.org/10.1007/s10661-023-11740-6 М22
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Synthesis, characterization, biomolecular interactions, molecular docking, and in vitro and in vivo anticancer activities of novel ruthenium(III) Schiff base complexes
Milica Međedović, Aleksandar Mijatović, Rada Baošić, Dejan Lazić, Žiko Milanović, Zoran Marković, Jelena Milovanović, Dragana Arsenijević, Bojana Stojanović, Miloš Arsenijević, Marija Milovanović, Biljana Petrović, Ana Rilak Simović (2023)In order to discover new anticancer drugs, novel ruthenium(III) complexes [Ru(L)Cl(H2O)], where L is tetradentate Schiff base bis(acetylacetone)ethylendiimine (acacen, 1), bis(benzoylacetone)ethylendiimine (bzacen, 2), (acetylacetone)(benzoylaceton)ethylendiimine (acacbzacen, 3), bis(acetylacetone)propylendiimine (acacpn, 4), bis(benzoylacetone)propylendiimine (bzacpn, 5) or (acetylacetone)(benzoylaceton)propylendiimine (acacbzacpn, 6), were synthesized. The complexes 1 – 6 were characterized by elemental analysis, molar conductometry, and by various spectroscopic techniques, such as UV–Vis, IR, EPR, and ESI-MS. Based on in vitro DNA/BSA experiments, complexes 2 (bzacen) and 5 (bzacpn) with two aromatic rings showed ...Milica Međedović, Aleksandar Mijatović, Rada Baošić, Dejan Lazić, Žiko Milanović, Zoran Marković, Jelena Milovanović, Dragana Arsenijević, Bojana Stojanović, Miloš Arsenijević, Marija Milovanović, Biljana Petrović, Ana Rilak Simović. "Synthesis, characterization, biomolecular interactions, molecular docking, and in vitro and in vivo anticancer activities of novel ruthenium(III) Schiff base complexes" in Journal of Inorganic Biochemistry, Elsevier BV (2023). https://doi.org/10.1016/j.jinorgbio.2023.112363 М21
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Freeze-dried nanocrystal dispersion of novel deuterated pyrazoloquinolinone ligand (DK-I-56-1): Process parameters and lyoprotectant selection through the stability study
Jelena R. Mitrović, Maja Bjelošević Žiberna, Aleksandar Vukadinović, Daniel E. Knutson, Dishary Sharmin, Aleksandar Kremenović, Pegi Ahlin Grabnar, Odon Planinšek, Dominique Lunter, James M. Cook, Miroslav M. Savić, Snežana D. Savić (2023)Recently, nanocrystal dispersions have been considered as a promising formulation strategy to improve the bioavailability of the deuterated pyrazoloquinolinone ligand DK-I-56-1 (7‑methoxy-2-(4‑methoxy-d3-phenyl)-2,5-dihydro-3H-pyrazolo[4,3-c]quinolin-3-one). In the current study, the freeze-drying process (formulation and process parameters) was investigated to improve the storage stability of the previously developed formulation. Different combinations of lyoprotectant (sucrose or trehalose) and bulking agent (mannitol) were varied while formulations were freeze-dried under two conditions (primary drying at -10 or -45 °C). The obtained lyophilizates were characterized in terms ...Jelena R. Mitrović, Maja Bjelošević Žiberna, Aleksandar Vukadinović, Daniel E. Knutson, Dishary Sharmin, Aleksandar Kremenović, Pegi Ahlin Grabnar, Odon Planinšek, Dominique Lunter, James M. Cook, Miroslav M. Savić, Snežana D. Savić. "Freeze-dried nanocrystal dispersion of novel deuterated pyrazoloquinolinone ligand (DK-I-56-1): Process parameters and lyoprotectant selection through the stability study" in European Journal of Pharmaceutical Sciences, Elsevier BV (2023). https://doi.org/10.1016/j.ejps.2023.106557 М21
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Distribution of Uranium and Rare Elements in Radioactive Phosphate-Bearing Anomalies in Southeast Mongolia
Boris Vakanjac, Neil Rutherford, Vesna Ristić Vakanjac, Tanita Đumić, Suzana Đorđević Milošević (2020)Soviet and Mongolian geologists initiated geological exploration of Mongolia for minerals after World War II (1945). These activities lasted until the breakup of the USSR in 1991. As part of this exploration systematic uranium and rare element exploration was undertaken across Mongolia. New exploration resumed in Mongolia at the beginning of the 21st century for a range of ore and mineral deposit styles including uranium, coal, base and precious metals and Fe-ore. This was generally undertaken by Western-based companies. This ...Boris Vakanjac, Neil Rutherford, Vesna Ristić Vakanjac, Tanita Đumić, Suzana Đorđević Milošević. "Distribution of Uranium and Rare Elements in Radioactive Phosphate-Bearing Anomalies in Southeast Mongolia" in Minerals, MDPI AG (2020). https://doi.org/10.3390/min10040307 М22
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Hydrographic and hydrological characterization of the Vodenička and Rosomačka rivers
Vesna Ristić Vakanjac, Marina Čokorilo Ilić, Dušan Polomčić, Dragoljub Bajić, Jelena Ratković (2017)The Visočica River rises in Bulgaria, on the Berovo Mountain. Its course in Bulgaria is 16.7 km long. It enters Serbia near the village of Donji Krivodol. Up to the village of Pakleštica, or the beginning of Lake Zavoj, its right-bank tributaries are the Krivodolštica, the Vodenička, the Rosomačka and the Dojkinačka. There are no left-bank tributaries. Among the tributaries, water levels and discharges are gauged only on the Dojkinačka River. The Vodenička had also been gauged but only ...Vesna Ristić Vakanjac, Marina Čokorilo Ilić, Dušan Polomčić, Dragoljub Bajić, Jelena Ratković. "Hydrographic and hydrological characterization of the Vodenička and Rosomačka rivers" in Pirotski zbornik, Pirot : Narodna biblioteka Pirot (2017). https://doi.org/10.5937/pirotzbor1742001R M53
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Geonasleđe Golije i Peštera
Ljiljana V. Grujičić-Tešić (2017-09-01)Sprovedena istraživanja u ovoj studiji obuhvatila su izdvajanje, opis, evaluaciju i valorizaciju objekata geonasleđa u cilju razvoja istraživane oblasti sa stanovišta geonauka, geoturizma i geoekologije. Na izučavanom području objekti geonasleđa su evidentirani, interpretirani, vrednovani i kategorisani, dat je predlog promocije geoobjekata, i na kraju predložena dopuna inventara objekata geonasleđa Srbije.U protekle četiri godine, na kompleksu geotopa Golije i Peštera istražena su geološka svojstva stena (tip stene, starost, fosilni sadržaj, morfološke i hidrogeološke karakteristike itd.), na osnovu čega je bilo ...Ljiljana V. Grujičić-Tešić. "Geonasleđe Golije i Peštera" in Универзитет у Београду, Универзитет у Београду, Рударско-геолошки факултет (2017-09-01)
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Минерагенија зеолитских туфова Србије
Vladan Kašić (2018-02-05)Лежишта наших зеолитских туфова (Златокоп, Игрош, Јабланица 1, Беочин, Топоница и Сланци) која су овде била предмет детаљних истраживања, просторно и генетски везана су за вулканске и вулканокластичне стене маринских средина сенонске и неогенске старости и језерске седименте неогене старости и настала су као продукт девитрификације вулканског стакла.Током лабораторијских испитивања при изради ове докторске дисертације, примењене су следеће аналитичке методе: оптичка испитивања петрографских препарата; рендгенска дифракција праха (XRD); скенирајућа електронска микроскопија (СЕМ метода); хемијска карактеризација зеолитских туфова у оквиру ...Vladan Kašić. "Минерагенија зеолитских туфова Србије" in Универзитет у Београду, Универзитет у Београду, Рударско-геолошки факултет (2018-02-05)
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SASA Dictionary as the Gold Standard for Good Dictionary Examples for Serbian
Ranka Stanković, Branislava Šandrih, Rada Stijović, Cvetana Krstev, Duško Vitas, Aleksandra Marković (2019)У овом раду представљамо модел за избор добрих примера за речник српског језика и развој иницијалних компоненти модела. Метода која се користи заснива се на детаљној анализи различитих лексичких и синтактичких карактеристика у корпусу састављених од примера из пет дигитализованих свезака речника САНУ. Почетни скуп функција био је инспирисан сличним приступом и за друге језике. Дистрибуција карактеристика примера из овог корпуса упоређује се са карактеристиком дистрибуције узорака реченица ексцерпираних из корпуса који садрже различите текстове. Анализа је показала да ...Српски, добри примери из речника, аутоматизација израде речника, издвајање својстава, Машинско учењеRanka Stanković, Branislava Šandrih, Rada Stijović, Cvetana Krstev, Duško Vitas, Aleksandra Marković. "SASA Dictionary as the Gold Standard for Good Dictionary Examples for Serbian" in Electronic lexicography in the 21st century. Proceedings of the eLex 2019 conference , Lexical Computing CZ, s.r.o. (2019) М33
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Utilizing sewage wastewater heat in district heating systems in Serbia: effects on sustainability
Marija Živković, Dejan Ivezić (2021)Transformation of the heating sector is recognized as being essential for ensuring reliable and afordable energy services provided with reduced consumption of energy sources and diminished impact on the environment and less import dependency. The possibility of utilizing energy sources that otherwise would be wasted needs to be considered and treated as a big advantage of district heating systems. Despite many advantages, sewage wastewater heat is still a mostly unused resource at the global level and a totally unused ...рекуперација топлоте из отпадних вода, систем даљинског грејања, топлотне пумпе, енергетске уштеде, емисија угљендиоксида, енергетска безбедност, СрбијаMarija Živković, Dejan Ivezić. "Utilizing sewage wastewater heat in district heating systems in Serbia: effects on sustainability" in Clean Technologies and Environmental Policy, Springer Science and Business Media LLC (2021). https://doi.org/10.1007/s10098-021-02063-6 М22
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The interaction of organoselenium trans-palladium(II) complexes toward small-biomolecules and CT-DNA
Serija organoselenijum trans-paladijum(II) kompleksa 1 (bis(2-(fenilselanilmetil)oksolan)dihloropaladijum(II)), 2 (bis(2-(fenilselanilmetil)oksan)dihloropaladijum(II)) i 3 (bis(2) ,2-dimetil-3-(fenilselanil)oksan)dihloropaladijum(II)) su korišćeni za ispitivanje reaktivnosti ovog specifičnog tipa kompleksa prema različitim bio-molekulima. Ovaj sistem je od posebnog interesa jer se jako malo zna o supstitucionim reakcijam organoselenijum paladijum(II) kompleksa sa trans konfiguracijom. Zamena koordinovanog hlorida sa serijom malih bio-molekula (l-Met, l-His, l-Cis, GSH i 5′-GMP) proučavana je pod uslovima pseudo-prvog reda kao funkcija koncentracije nukleofila i temperature korišćenjem tehnika zaustavljenog toka. Rezultati za proučavane komplekse ukazuju da ...Vera M. Divac, Aleksandar Mijatović, Marina D. Kostić, Jovana Bogojeski. "The interaction of organoselenium trans-palladium(II) complexes toward small-biomolecules and CT-DNA" in Inorganica Chimica Acta, Elsevier BV (2017). https://doi.org/10.1016/j.ica.2017.07.012 М22
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Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles
Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović (2013)Kinetika i mehanizam reakcija supstitucije između [Ru(trpi)(bpi)Cl]+ sa nukleofilima gvanozin-5′-monofosfatom, L-histidinom, tioureom i dimetilsulfoksidom proučavani su spektrofotometrijski u 0,1 M NaClO4 na 310 K. Red reaktivnosti za odabrane ligande je: tiourea > gvanozin-5′-monofosfat > L-histidin > DMSO. Ovaj red je povezan sa elektronskim, strukturnim i hemijskim karakteristikama kompleksa i nukleofila. Reakcija supstitucije sa tioureom je proučavana na tri različite temperature (288, 298 i 310 K). Negativna entropija aktivacije DS = potvrđuje asocijativni način aktivacije. Formiranje kompleksa [Ru(trpi)(bpi)H2O]2+ sa ligandima ...Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović. "Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles" in Monatshefte für Chemie - Chemical Monthly, Springer Science and Business Media LLC (2013). https://doi.org/10.1007/s00706-013-1044-1 М22
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Cretaceous ultrapotassic magmatism from the Sava-Vardar Zone of the Balkans
Kristijan Sokol, Dejan Prelević, Rolf Romer, Milica Božović, Paul van den Bogaard, Elitsa Stefanova, Bojan Kostić, Nenad Čokulov (2020)Late Cretaceous global plate reorganization associated with the inception of counterclockwise rotation of Africa relative to Europe initiated in the Balkan region small-volume magmatism of diverse geochemical signature along the enigmatic Sava-Vardar Zone. We study a Late Cretaceous lamprophyric sill in Ripanj village near Belgrade to constrain this magmatic episode. The lamprophyre is characterized by high contents of Na, P, Fe and Al, and low contents of K, Ca and Mg. Its original nature (Na, K, Ca and Mg) is ...Kristijan Sokol, Dejan Prelević, Rolf Romer, Milica Božović, Paul van den Bogaard, Elitsa Stefanova, Bojan Kostić, Nenad Čokulov. "Cretaceous ultrapotassic magmatism from the Sava-Vardar Zone of the Balkans" in Lithos (2020) М21а
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Development of the hybrid MCDM model for evaluating and selecting bucket wheel excavators for the modernization process
This paper presents a methodology for evaluating and ranking different bucket wheel excavators (BWE) for determining which machine should enter in the process of revitalization and modernization. Various multicriteria methods are used. Combining them achieves the best effect when choosing BVE for the modernization process. AHP, TOPSIS, VIKOR, and PROMETHEE methods are used. The hybrid models are developed from the multi-criteria decision making (MCDM) methods and they are used to evaluate the basic indicators that characterize the operation of ...Snezana Savkovic, Predrag Jovancic, Stevan Djenadic, Milos Tanasijevic, Filip Miletic. "Development of the hybrid MCDM model for evaluating and selecting bucket wheel excavators for the modernization process" in Expert Systems with Applications, Elsevier BV (2022). https://doi.org/10.1016/j.eswa.2022.117199 М21а
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Hydrochemical indicators of groundwater flow in the area of “Čukaru Peki” Cu-Au underground mine in eastern Serbia
The physical and chemical properties of groundwater, together with the groundwater levels regime and rock hydraulic properties, are often used to understand and conceptualize the hydrogeological system. Prediction of the influence of mining works on groundwater, and vice versa, is a challenge due to significantly altered groundwater flow patterns in the raw materials exploitation areas in relation to natural conditions. Therefore, multiple parameters are assessed and monitored before and during exploitation to properly characterize and quantify the system for ...Nebojša Atanacković, Vladimir Živanović, Jana Štrbački, Veselin Dragišić, Ivana Cvejić. "Hydrochemical indicators of groundwater flow in the area of “Čukaru Peki” Cu-Au underground mine in eastern Serbia" in 5th IAH CEG conference, Slovenian Committee of International Association of Hydrogeologists - SKIAH (2022) М34
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Complex geophysical survey on solving the problem of water loss in the karst terrain reservoir
Branislav Sretković, Dejan Vučković (2023)Geophysical surveys in karst terrain are always a specific challenge. Each of them requires a careful consideration of the problem, specific conditions on the ground, the selection of adequate methods applicable in that specific and unique karst area. But they should have one thing in common: a complex approach and looking at the problem from wider to narrower, with a gradual narrowing of the investigation area, increasing the spatial precision and resolution of the obtained data. On the example of ...Branislav Sretković, Dejan Vučković. "Complex geophysical survey on solving the problem of water loss in the karst terrain reservoir" in 8th Symposium Geoscience 2023, Bucharest, 9-11. November 2023, Bucharest : Editura Cetatea de Scaun (2023) М34